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基质吸力 2

非饱和土 2

Au/Ti双功能催化剂 1

H₂有效利用率 1

丙烯环氧化 1

体积含水量 1

塑性体应变与剪应变的相互作用原理 1

密度泛函理论 1

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Behavior of materials for earth and rockfill dams: Perspective from unsaturated soil mechanics

Eduardo E. ALONSO, Rafaela CARDOSO,

《结构与土木工程前沿（英文）》 2010年第4卷第1期页码 1-39 doi: 10.1007/s11709-010-0013-6

摘要： The basis of the design of earth and rockfill dams is focused on ensuring the stability of the structure under a set of conditions expected to occur during its life. Combined mechanical and hydraulic conditions must be considered since pore pressures develop during construction, after impoundment and in drawdown. Other instability phenomena caused by transient flow and internal erosion must be considered. The prediction of the hydro-mechanical behavior of traditional and non-traditional materials used in the construction of dams is therefore fundamental. The materials used for dam’s construction cover a wide range from clayey materials to rockfill. In a broad sense they are compacted materials and therefore unsaturated materials. A summary of the current level of knowledge on the behavior of traditional materials used in the construction of dams is presented in the paper. Regular compacted materials (with a significant clay fraction), rockfill and compacted soft rocks are studied with more detail. The latter are non-traditional materials. They are analysed because their use, as well as the use of mixtures of soil and rock, is becoming more necessary for sustainability reasons.

关键词： dams unsaturated soil mechanics suction rockfill clayey soil mixture

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Application of fractal theory to unsaturated soil mechanics

XU Yongfu, TONG Lixin

《结构与土木工程前沿（英文）》 2007年第1卷第4期页码 411-421 doi: 10.1007/s11709-007-0056-5

摘要： The mechanical properties of unsaturated soils are a function of the saturation degree or matric suction, and can be obtained based on currently available procedures. However, each procedure has its limitations and consequently, care should be taken in the selection of a proper procedure. The fractal approach seems to be a potentially useful tool to describe hierarchical systems and is suitable to model the structure and hydraulic properties of unsaturated soils. In this paper, the soil-water characteristics, unsaturated hydraulic conductivity function, unsaturated shear strength, swelling deformation and compression were derived from the fractal model for the pore-size distribution, and were expressed by only two independent physical parameters, the fractal dimension and the air entry value. The predictions of the proposed soil-water characteristics, unsaturated hydraulic conductivity, unsaturated shear strength, swelling deformation and compression were in good agreement with published experimental data. Comparisons between the experimental results of unsaturated hydraulic conductivity and the predictions of the both fractal model and the van Genuchten-Mualem model were also performed, and it was found that the predictions of the fractal model were better than that of the van Genuchten-Mualem model.

关键词： selection soil-water independent physical unsaturated strength

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Soil-water interaction in unsaturated expansive soil slopes

ZHAN Liangtong

《结构与土木工程前沿（英文）》 2007年第1卷第2期页码 198-204 doi: 10.1007/s11709-007-0023-1

摘要： The intensive soil-water interaction in unsaturated expansive soil is one of the major reasons for slope failures. In this paper, the soil-water interaction is investigated with the full-scale field inspection of rainwater infiltration and comprehensive experiments, including wetting-induced softening tests, swelling, and shrinkage tests. It is demonstrated that the soil-water interaction induced by seasonal wetting-drying cycles is very complex, and it involves coupled effects among the changes in water content, suction, stress, deformation and shear strength. In addition, the abundant cracks in the expansive soil play an important role in the soil-water interaction. The cracks disintegrate the soil mass, and more importantly, provide easy pathways for rainfall infiltration. Infiltration of rainwater not only results in wetting-induced softening of the shallow unsaturated soil layers, but also leads to the increase of horizontal stress. The increase of horizontal stress may lead to a local passive failure. The seasonal wetting-drying cycles tend to result in a down-slope creeping of the shallow soil layer, which leads to progressive slope failure.

关键词： strength intensive soil-water comprehensive Infiltration wetting-induced softening

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Stability analysis of layered slopes in unsaturated soils

Guangyu DAI; Fei ZHANG; Yuke WANG

《结构与土木工程前沿（英文）》 2022年第16卷第3期页码 378-387 doi: 10.1007/s11709-022-0808-2

摘要： This study presents stability analyses of layered soil slopes in unsaturated conditions and uses a limit equilibrium method to determine the factor of safety involving suction stress of unsaturated soil. One-dimensional steady infiltration and evaporation conditions are considered in the stability analyses. An example of a two-layered slope in clay and silt is selected to verify the used method by comparing with the results of other methods. Parametric analyses are conducted to explore the influences of the matric suction on the stability of layered soil slopes. The obtained results show that larger suction stress provided in unsaturated clay dominates the stability of the layered slopes. Therefore, the location and thickness of the clay layer have significant influences on slope stability. As the water level decreases, the factor of safety reduces and then increases gradually in most cases. Infiltration/evaporation can obviously affect the stability of unsaturated layered slopes, but their influences depend on the soil property and thickness of the lower soil layer.

关键词： slope stability suction stress unsaturated soil layered slope limit equilibrium

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Assessment of future climate change impacts on water-heat-salt migration in unsaturated frozen soil using

Hanli Wan, Jianmin Bian, Han Zhang, Yihan Li

《环境科学与工程前沿（英文）》 2021年第15卷第1期 doi: 10.1007/s11783-020-1302-5

摘要： Abstract • A model coupling water-heat-salt of unsaturated frozen soil was established. • Future temperature, precipitation, and evaporation increase in freeze–thaw period. • Soil water, heat, and salt transport are closely coupled during freeze–thaw period. • Freeze–thaw cycles and future climate change can exacerbate salinization. The transport mechanisms of water, heat, and salt in unsaturated frozen soil, as well as its response to future climate change are in urgent need of study. In this study, western Jilin Province in north-eastern China was studied to produce a model of coupled water-heat-salt in unsaturated frozen soil using CoupModel. The water, heat, and salt dynamics of unsaturated frozen soil under three representative concentration pathway (RCP) scenarios were simulated to analyze the effects of future climate change on unsaturated frozen soil. The results show that water, heat, and salt migration are tightly coupled, and the soil salt concentration in the surface layer (10 cm) exhibits explosive growth after freezing and thawing. The future (2020–2099) meteorological factors in the study area were predicted using the Statistical Downscaling Model (SDSM). For RCP2.6, RCP4.5, and RCP8.5 scenarios, future temperatures during the freeze–thaw period increased by 2.68°C, 3.18°C, and 4.28°C, respectively; precipitation increased by 30.28 mm, 28.41 mm, and 32.17 mm, respectively; and evaporation increased by 93.57 mm, 106.95 mm, and 130.57 mm, respectively. Climate change will shorten the freeze–thaw period, advance the soil melting time from April to March, and enhance water and salt transport. Compared to the baseline period (1961–2005), future soil salt concentrations at 10 cm increased by 1547.54 mg/L, 1762.86 mg/L, and 1713.66 mg/L under RCP2.6, RCP4.5, and RCP8.5, respectively. The explosive salt accumulation is more obvious. Effective measures should be taken to prevent the salinization of unsaturated frozen soils and address climate change.

关键词： Soil salinization Climate change Unsaturated frozen soil Water-heat-salt balance Soil environment change

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Stable expression and control parameters in the numerical simulation of unsaturated flow

Zhiyuan ZHANG; Xu LI; Yongkang WU; Xiaokang LI

《结构与土木工程前沿（英文）》 2022年第16卷第12期页码 1501-1514 doi: 10.1007/s11709-022-0893-2

摘要： The Richards’ equation describes the flow phenomenon in unsaturated porous media and is essential to hydrology and environmental science. This study evaluated the numerical stability of two different forms of the Richards’ equation. Sensitivity analyses were performed to investigate the control parameters of the equation. The results show that the h-form Richards’ equation has better applicability for calculating variable saturation flows than the θ-form Richards’ equation. For the h-form Richards’ equation, the hydraulic conductivity of the soil in the low-suction range and the specific moisture capacity in the high-suction range primarily influenced the solution. In addition, sensitivity analyses indicated that the saturated hydraulic conductivity, initial condition, and air-entry pressure have a higher sensitivity to the simulation results than the saturated water content, rainfall intensity, and decline rate of hydraulic conductivity. Moreover, their correctness needs to be guaranteed first in numerical simulations. The research findings can provide a helpful reference for improving the reliability of numerical simulations of unsaturated flows.

关键词： Richards’ equation sensitivity analysis unsaturated soil hydraulic diffusivity seepage simulation

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Determination of effective stress parameter of unsaturated soils: A Gaussian process regression approach

Pijush Samui, Jagan J

《结构与土木工程前沿（英文）》 2013年第7卷第2期页码 133-136 doi: 10.1007/s11709-013-0202-1

摘要： This article examines the capability of Gaussian process regression (GPR) for prediction of effective stress parameter ( ) of unsaturated soil. GPR method proceeds by parameterising a covariance function, and then infers the parameters given the data set. Input variables of GPR are net confining pressure ( ), saturated volumetric water content ( ), residual water content ( ), bubbling pressure ( ), suction ( ) and fitting parameter ( ). A comparative study has been carried out between the developed GPR and Artificial Neural Network (ANN) models. A sensitivity analysis has been done to determine the effect of each input parameter on . The developed GPR gives the variance of predicted . The results show that the developed GPR is reliable model for prediction of of unsaturated soil.

关键词： unsaturated soil effective stress parameter Gaussian process regression (GPR) artificial neural network (ANN) variance

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Effect of a less permeable stronger soil layer on the stability of non-homogeneous unsaturated slopes

Nabarun DEY, Aniruddha SENGUPTA

《结构与土木工程前沿（英文）》 2020年第14卷第6期页码 1462-1475 doi: 10.1007/s11709-020-0674-8

摘要： Slope failure occurs due to an increase in the saturation level and a subsequent decrease in matric suction in unsaturated soil. This paper presents the results of a series of centrifuge experiments and numerical analyses on a 55° inclined unsaturated sandy slope with less permeable, stronger silty sand layer inclusion within it. It is observed that a less permeable, stronger silty sand layer in an otherwise homogeneous sandy soil slope hinders the infiltration of water. The water content of the slope just above the stronger layer increases significantly, compared to elsewhere. No shear band is found to initiate in a homogeneous sandy soil slope, whereas for a non-homogeneous slope, they initiate just above the less pervious, stronger layer. A discontinuity of the shear zone is also observed for the case of a non-homogeneous soil slope. The factor of safety of a non-homogeneous, unsaturated soil slope decreases because of the less permeable, stronger layer. It decreases significantly if this less permeable, stronger soil layer is located near the toe of the slope.

关键词： non-homogeneous slope stronger soil layer factor of safety centrifuge model test unsaturated soils

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Carbon-doped surface unsaturated sulfur enriched CoS@rGO aerogel pseudocapacitive anode and biomass-derived

《化学科学与工程前沿（英文）》 2021年第15卷第6期页码 1500-1513 doi: 10.1007/s11705-021-2086-2

摘要： As a hybrid energy storage device of lithium-ion batteries and supercapacitors, lithium-ion capacitors have the potential to meet the demanding needs of energy storage equipment with both high power and energy density. In this work, to solve the obstacle to the application of lithium-ion capacitors, that is, the balancing problem of the electrodes kinetic and capacity, two electrodes are designed and adequately matched. For the anode, we introduced in situ carbon-doped and surface-enriched unsaturated sulfur into the graphene conductive network to prepare transition metal sulfides, which enhances the performance with a faster lithium-ion diffusion and dominant pseudocapacitive energy storage. Therefore, the lithium-ion capacitors anode material delivers a remarkable capacity of 810 mAh∙g^–1 after 500 cycles at 1 A∙g^–1. On the other hand, the biomass-derived porous carbon as the cathode also displays a superior capacity of 114.2 mAh∙g^–1 at 0.1 A∙g^–1. Benefitting from the appropriate balance of kinetic and capacity between two electrodes, the lithium-ion capacitors exhibits superior electrochemical performance. The assembled lithium-ion capacitors demonstrate a high energy density of 132.9 Wh∙kg^–1 at the power density of 265 W∙kg^–1, and 50.0 Wh∙kg^–1 even at 26.5 kW∙kg^–1. After 10000 cycles at 1 A∙g^–1, lithium-ion capacitors still demonstrate the high energy density retention of 81.5%.

关键词： in-situ carbon-doped surface unsaturated sulfur enriched pseudocapacitive energy storage biomass-derived carbon lithium-ion capacitors

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vanadium-bearing resources in the preparation of rare-earth vanadate catalysts for semi-hydrogenation of ,-unsaturated

《化学科学与工程前沿（英文）》 2022年第16卷第12期页码 1793-1806 doi: 10.1007/s11705-022-2191-x

摘要： Recycling industrial solid waste not only saves resources but also eliminates environmental concerns of toxic threats. Herein, we proposed a new strategy for the utilization of petrochemical-derived carbon black waste, a waste vanadium-bearing resource (V > 30000 ppm (10 ⁻⁶)). Chemical leaching was employed to extract metallic vanadium from the waste and the leachate containing V was used as an alternative raw material for the fabrication of vanadate nanomaterials. Through the screening of various metal cations, it was found that the contaminated Na⁺ during the leaching process showed strong competitive coordination with the vanadium ions. However, by adding foreign Ce³⁺ and Y³⁺ cations, two rare-earth vanadates, viz., flower-like CeVO₄ and spherical YVO₄ nanomaterials, were successfully synthesized. Characterization techniques such as scanning electron microscopy, transmission electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, Fourier-transform infrared, and N₂ physisorption were applied to analyze the physicochemical properties of the waste-derived nanomaterials. Importantly, we found that rare-earth vanadate catalysts exhibited good activities toward the semi-hydrogenation of α,β-unsaturated aldehydes. The conversion of cinnamaldehyde and cinnamic alcohol selectivity were even higher than those of the common CeVO₄ prepared using pure chemicals (67.2% vs. 27.7% and 88.4% vs. 53.5%). Our work provides a valuable new reference for preparing vanadate catalysts by the use of abundant vanadium-bearing waste resources.

关键词： petrochemical solid wastes vanadium recovery resource utilization nanomaterials semi-hydrogenation

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非饱和土的塑性体应变与剪应变的相互作用原理

王靖涛

《中国工程科学》 2007年第9卷第11期页码 11-15

摘要：

将岩土塑性体应变与剪应变的相互作用原理拓展到了非饱和土领域。除了塑性体应变与剪应变的相互作用外，在非饱和土中出现了两类新的相互作用，吸力-塑性体应变和孔隙气压力-塑性体应变。吸力具有二重性质，其对塑性体应变作用包括两个相反的方面。基于吸力性质，阐明了非饱和土的一些独特的性质，诸如有效应力参数的物理涵义，吸力对体积变化和前期固结压力的影响和湿陷机理等。另外，应用拓展的塑性体应变与剪应变相互作用原理，从理论上证明了非饱和土的临界状态线是存在的和唯一的，以及它与应力历史无关。

关键词：塑性体应变与剪应变的相互作用原理非饱和土基质吸力有效应力原理

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非饱和土坡危险含水量分析

张士林,王冬梅,李根华

《中国工程科学》 2004年第6卷第5期页码 71-75

摘要：

介绍了由于雨水入渗，使非饱和土坡的含水量发生变化，而含水量正是与基质吸力有着直接的联系；同时通过分析条件水压力和非饱和土的容重与含水量的变化规律，得到基质吸力、饱和度、非饱和土容重与整个土坡的稳定性规律，也就是安全系数与含水量分布的规律。得出当土坡处于危险状况下的含水量分布，即当土坡中的含水量达到危险含水量时，土坡处于危险状态。因此，通过监测土坡的含水量的变化，获得土坡的稳定信息，为生产和安全提供保障。

关键词：非饱和土稳定性分析降雨入渗体积含水量基质吸力

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Stress-strain relationship with soil structural parameters of collapse loess

SHAO Shengjun, LONG Jiyong, YU Qinggao

《结构与土木工程前沿（英文）》 2008年第2卷第2期页码 151-160 doi: 10.1007/s11709-008-0020-z

摘要： Through the tri-axial shearing tests of unsaturated intact loess and based on the concept of comprehensive soil structural potential, this paper reveals the changing laws of soil structural property under the tri-axial stress conditions and establishes a mathematical expression equation of structural parameters, whereby reflecting the effects of unsaturated loess water content, stress and strain states, which is introduced into the shearing stress and shearing strain relation to obtain the structural stress-strain relation. The tests reveal that the loess dilatancy is of shearing contraction and shearing expansion, whereby indicating that there is a good linear relation between the stress ratio and shearing expansion strain ratio. The larger consolidation confining pressure is, the larger the stress of shearing contraction and expansion critical point is; and the larger water content is, the smaller the strain ratio of shearing contraction and expansion critical point is. Finally, the constitutive model is established to reflect the variation in loess structure, stress-strain softening and hardening, and shearing contraction and shearing expansion features. Through the comparative analysis, the stress-strain curves described by the constitutive relationship are found to be in good conformity with test results, whereby testing the rationality of the model in this paper.

关键词： hardening shearing expansion unsaturated structural property mathematical expression

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“Partial pressures” of humid air in wide pressure and temperature ranges

Zidong WANG, Hanping CHEN, Shilie WENG

《能源前沿（英文）》 2013年第7卷第4期页码 511-517 doi: 10.1007/s11708-013-0281-7

摘要： “Partial pressure” in humid air is a question very much concerned by scientists and no satisfactory answer has been found to date. This paper proposes a novel method to obtain the “partial pressures” of the water vapor and dry air in humid air. The results obtained by the proposed method are quite different from that obtained by Dalton’s partial pressure law. The fundamental behaviors of water vapor and dry air are studied in depth in wide pressure and temperature ranges. Semi-permeable membrane models are proposed and applied for both saturated and unsaturated humid air. “Improvement factors” are developed to quantitatively describe the magnitude of the interaction between dissimilar molecules. One discovery is that the “partial pressure” of the water vapor in saturated humid air equals , rather than ( · ) which was formerly believed. The other is that the interaction between dissimilar molecules may be omitted when temperature is above “cutting-off temperature” for unsaturated humid air. This paper satisfactorily answers the quest of “partial pressures” in humid air from a new perspective.

关键词： partial pressure Dalton’s partial pressure law humid air saturated unsaturated

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Coupled solid-fluid FE-analysis of an embankment dam

Michael PERTL, Matthias HOFMANN, Guenter HOFSTETTER

《结构与土木工程前沿（英文）》 2011年第5卷第1期页码 53-62 doi: 10.1007/s11709-010-0084-4

摘要： A coupled solid-fluid FE-model for partially saturated soils, characterized by modeling the soil as a three-phase material consisting of a deformable soil skeleton and the fluid phases water and air, is reviewed briefly. As a constitutive model for the soil skeleton, the well-known Barcelona Basic model (BBM) is employed, which is formulated in terms of net stress and matric suction. For the BBM, a computationally efficient return mapping algorithm is proposed, which only requires the solution of a scalar nonlinear equation at the integration point level. The coupled FE-model is applied to the coupled transient numerical simulation of the water flow and the deformations and stresses in an embankment dam.

关键词： multi-phase model unsaturated soil model Barcelona Basic model (BBM) return mapping algorithm embankment dam