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Modeling of ion conductivity in Nafion membranes

YANG Zhen, PENG Xiaofeng, WANG Buxuan, DUAN Yuanyuan, LEE Duujong

《能源前沿(英文)》 2007年 第1卷 第1期   页码 58-66 doi: 10.1007/s11708-007-0005-y

摘要: A theoretical investigation was conducted to describe the ion transport behavior in a Nafion Membrane of proton exchange membrane fuel cells (PEMFC). By analyzing the surface energy configuration of the ionic clusters in a Nafion membrane, an equivalent field intensity, , was introduced to facilitate the analysis of surface resistance against ion conduction in the central region of clusters. An expression was derived for ionic conductivity incorporating the influence of surface resistance. A face-centered cubic (FCC) lattice model for a spatial cluster distribution was used to modify the effect of water content on ionic conductivity in the polymeric matrix, i.e., the regions between clusters. Compared with the available empirical correlations, the new expression showed much better agreement with the available experimental results, which indicates the rationality to consider the structural influence on ion conduction in water-swollen Nafion membranes.

关键词: face-centered     polymeric     theoretical investigation     conduction     equivalent    

Statistical modeling of radiolytic (

G. S. Muthu Iswarya, B. Nirkayani, A. Kavithakani, V. C. Padmanaban

《环境科学与工程前沿(英文)》 2019年 第13卷 第3期 doi: 10.1007/s11783-019-1126-3

摘要:

Linear, interactive and quadratic effects of process parameters were studied.

Degradation of Ofloxacin (Ofx) was related with G value of irradiation process.

The synergistic effect of H2O2 on lower dose of g-irradiation was established.

The process follows pseudo first order with dose constant (d = 0.232 kGy1).

关键词: Ofloxacin     Gamma irradiation     Face centered central composite design     Reaction kinetics     Gas Chromatography-Mass spectrum    

Strengthening of the concrete face slabs of dams using sprayable strain-hardening fiber-reinforced cementitious

《结构与土木工程前沿(英文)》 2022年 第16卷 第2期   页码 145-160 doi: 10.1007/s11709-022-0806-4

摘要: In this study, sprayable strain-hardening fiber-reinforced cementitious composites (FRCC) were applied to strengthen the concrete slabs in a concrete-face rockfill dam (CFRD) for the first time. Experimental, numerical, and analytical investigations were carried out to understand the flexural properties of FRCC-layered concrete slabs. It was found that the FRCC layer improved the flexural performance of concrete slabs significantly. The cracking and ultimate loads of a concrete slab with an 80 mm FRCC layer were 132% and 69% higher than those of the unstrengthened concrete slab, respectively. At the maximum crack width of 0.2 mm, the deflection of the 80-mm FRCC strengthened concrete slab was 144% higher than that of the unstrengthened concrete slab. In addition, a FE model and a simplified analytical method were developed for the design and analysis of FRCC-layered concrete slabs. Finally, the test result of FRCC leaching solution indicated that the quality of the water surrounding FRCC satisfied the standard for drinking water. The findings of this study indicate that the sprayable strain-hardening FRCC has a good potential for strengthening hydraulic structures such as CFRDs.

关键词: strain-hardening cementitious composites     engineered cementitious composites     sprayable     shotcrete     strengthening     concrete-face rockfill dam     digital image correlation    

Effect of cutterhead configuration on tunnel face stability during shield machine maintenance outages

《结构与土木工程前沿(英文)》 2023年 第17卷 第4期   页码 522-532 doi: 10.1007/s11709-023-0930-9

摘要: Owing to long-distance advancement or obstacles, shield tunneling machines are typically shut down for maintenance. Engineering safety during maintenance outages is determined by the stability of the tunnel face. Pressure maintenance openings are typically used under complicated hydrogeological conditions. The tunnel face is supported by a medium at the bottom of the excavation chamber and compressed air at the top. Owing to the high risk of face failure, the necessity of support pressure when cutterhead support is implemented and a method for determining the value of compressed air pressure using different support ratios must to be determined. In this study, a non-fully chamber supported rotational failure model considering cutterhead support is developed based on the upper-bound theorem of limit analysis. Numerical simulation is conducted to verify the accuracy of the proposed model. The results indicate that appropriately increasing the specific gravity of the supporting medium can reduce the risk of collapse. The required compressed air pressure increases significantly as the support ratio decreases. Disregarding the supporting effect of the cutterhead will result in a tunnel face with underestimated stability. To satisfy the requirement of chamber openings at atmospheric pressure, the stratum reinforcement strength and range at the shield end are provided based on different cutterhead aperture ratios.

关键词: tunnel face stability     cutterhead configuration     aperture ratio     pressure gradient     support ratio    

Method for solving the nonlinear inverse problem in gas face seal diagnosis based on surrogate models

《机械工程前沿(英文)》 2022年 第17卷 第3期 doi: 10.1007/s11465-022-0689-z

摘要: Physical models carry quantitative and explainable expert knowledge. However, they have not been introduced into gas face seal diagnosis tasks because of the unacceptable computational cost of inferring the input fault parameters for the observed output or solving the inverse problem of the physical model. The presented work develops a surrogate-model-assisted method for solving the nonlinear inverse problem in limited physical model evaluations. The method prepares a small initial database on sites generated with a Latin hypercube design and then performs an iterative routine that benefits from the rapidity of the surrogate models and the reliability of the physical model. The method is validated on simulated and experimental cases. Results demonstrate that the method can effectively identify the parameters that induce the abnormal signal output with limited physical model evaluations. The presented work provides a quantitative, explainable, and feasible approach for identifying the cause of gas face seal contact. It is also applicable to mechanical devices that face similar difficulties.

关键词: surrogate model     gas face seal     fault diagnosis     nonlinear dynamics     tribology    

Experimental study of face passive failure features of a shallow shield tunnel in coastal backfill sand

《结构与土木工程前沿(英文)》 2024年 第18卷 第2期   页码 252-271 doi: 10.1007/s11709-024-1059-1

摘要: Face passive failure can severely damage existing structures and underground utilities during shallow shield tunneling, especially in coastal backfill sand. In this work, a series of laboratory model tests were developed and conducted to investigate such failure, for tunnels located at burial depth ratios for which C/D = 0.5, 0.8, 1, and 1.3. Support pressures, the evolution of failure processes, the failure modes, and the distribution of velocity fields were examined through model tests and numerical analyses. The support pressure in the tests first rose rapidly to the elastic limit and then gradually increased to the maximum value in all cases. The maximum support pressure decreased slightly in cases where C/D = 0.8, 1, and 1.3, but the rebound was insignificant where C/D = 0.5. In addition, the configuration of the failure mode with C/D = 0.5 showed a wedge-shaped arch, which was determined by the outcropping shear failure. The configuration of failure modes was composed of an arch and the inverted trapezoid when C/D = 0.8, 1, and 1.3, in which the mode was divided into lower and upper failure zones.

关键词: tunnel face stability     passive failure     model test     support pressure     failure mode    

Real-time prediction of tunnel face conditions using XGBoost Random Forest algorithm

《结构与土木工程前沿(英文)》 2023年 第17卷 第12期   页码 1777-1795 doi: 10.1007/s11709-023-0044-4

摘要: Real-time perception of rock conditions based on continuously collected data to meet the requirements of continuous Tunnel Boring Machine (TBM) construction presents a critical challenge that warrants increased attention. To achieve this goal, this paper establishes real-time prediction models for fractured and weak rock mass by comparing 6 different algorithms using real-time data collected by the TBM. The models are optimized in terms of selecting metric, selecting input features, and processing imbalanced data. The results demonstrate the following points. (1) The Youden’s index and area under the ROC curve (AUC) are the most appropriate performance metrics, and the XGBoost Random Forest (XGBRF) algorithm exhibits superior prediction and generalization performance. (2) The duration of the TBM loading phase is short, usually within a few minutes after the disc cutter contacts the tunnel face. A model based on the features during the loading phase has a miss rate of 21.8%, indicating that it can meet the early warning needs of TBM construction well. As the TBM continues to operate, the inclusion of features calculated from subsequent data collection can continuously correct the results of the real-time prediction model, ultimately reducing the miss rate to 16.1%. (3) Resampling the imbalanced data set can effectively improve the prediction by the model, while the XGBRF algorithm has certain advantages in dealing with the imbalanced data issue. When the model gives an alarm, the TBM operator and on-site engineer can be reminded and take some necessary measures for avoiding potential tunnel collapse. The real-time predication model can be a useful tool to increase the safety of TBM excavation.

关键词: Tunnel Boring Machine     fractured and weak rock mass     machine learning model     real-time early warming     tunnel face rock condition    

Dynamic in-plane transversal normal stresses in the concrete face of CFRD

Neftalí SARMIENTO-SOLANO, Miguel P. ROMO

《结构与土木工程前沿(英文)》 2019年 第13卷 第1期   页码 135-148 doi: 10.1007/s11709-018-0481-7

摘要: Severe earthquakes can induce damages to Concrete Face Rockfill Dams (CFRDs) such as concrete cracking and joint's water stops distressing where high in-plane transversal normal stresses develop. Although these damages rarely jeopardize the dam safety, they cause large water reservoir leakages that hinder the dam functioning. This issue can be addressed using well know numerical methods; however, given the wide range of parameters involved, it would seem appropriate to develop a simple yet reliable procedure to get a close understanding how their interaction affects the CFRD’s overall behavior. Accordingly, once the physics of the problem is better understood one can proceed to perform a detailed design of the various components of the dam. To this end an easy-to-use procedure that accounts for the dam height effects, valley narrowness, valley slopes, width of concrete slabs and seismic excitation characteristics was developed. The procedure is the dynamic complement of a method recently developed to evaluate in-plane transversal normal stresses in the concrete face of CFRD’s due to dam reservoir filling [ ]. Using these two procedures in a sequential manner, it is possible to define the concrete slab in-plane normal stresses induced by the reservoir filling and the action of orthogonal horizontal seismic excitations acting at the same time upstream-downstream and cross river. Both procedures were developed from a data base generated using nonlinear static and dynamic three-dimensional numerical analyses on the same group of CFRD’s. Then, the results were interpreted with the Buckingham Pi theorem and various relationships were developed. In the above reference, the method to evaluate the concrete face in-plane transversal normal stresses caused by the first reservoir filling was reported. In this paper, the seismic procedure is first developed and then through an example the whole method (dam construction, reservoir filling plus seismic loading) of analysis is assessed.

关键词: CFR dams     dynamic analysis     in-plane normal stresses     concrete face    

Local uncorrelated local discriminant embedding for face recognition

Xiao-hu MA,Meng YANG,Zhao ZHANG

《信息与电子工程前沿(英文)》 2016年 第17卷 第3期   页码 212-223 doi: 10.1631/FITEE.1500255

摘要: The feature extraction algorithm plays an important role in face recognition. However, the extracted features also have overlapping discriminant information. A property of the statistical uncorrelated criterion is that it eliminates the redundancy among the extracted discriminant features, while many algorithms generally ignore this property. In this paper, we introduce a novel feature extraction method called local uncorrelated local discriminant embedding (LULDE). The proposed approach can be seen as an extension of a local discriminant embedding (LDE) framework in three ways. First, a new local statistical uncorrelated criterion is proposed, which effectively captures the local information of interclass and intraclass. Second, we reconstruct the affinity matrices of an intrinsic graph and a penalty graph, which are mentioned in LDE to enhance the discriminant property. Finally, it overcomes the small-sample-size problem without using principal component analysis to preprocess the original data, which avoids losing some discriminant information. Experimental results on Yale, ORL, Extended Yale B, and FERET databases demonstrate that LULDE outperforms LDE and other representative uncorrelated feature extraction methods.

关键词: Feature extraction     Local discriminant embedding     Local uncorrelated criterion     Face recognition    

In-plane transversal normal stresses in the concrete face of CFRD induced by the first-dam reservoir

Neftalí SARMIENTO-SOLANO, Miguel P. ROMO

《结构与土木工程前沿(英文)》 2018年 第12卷 第1期   页码 81-91 doi: 10.1007/s11709-016-0378-2

摘要: To evaluate the effects of dam height, valley narrowness and width of concrete slabs on the first-dam reservoir filling in-plane transversal normal stresses in the concrete face of CFRD´s, 3D finite difference analyses were carried out. Behavior of rockfill dams considered in this study was defined from the monitoring of a number of 3D sets of pressure cells and extensometers installed in three large dams in Mexico. The 3D analyses results show that high in-plane transversal compressive stresses develop within the concrete panels located in the central concrete face zone upon dam reservoir filling loading. Likewise, in-plane induced tensile transversal stresses in the zones near the abutments increase the potential of slabs cracking and damaging the waterstops in-between the vertical and perimetral joints. From the results of the 3D finite difference analyses, a simple method to estimate in-plane normal stresses in the concrete face is advanced and through comparisons with the results of a 3D case numerical study, its accuracy assessed.

关键词: concrete face     CFR dams     reservoir filling     slab in-plane stresses    

Model test and discrete element method simulation of shield tunneling face stability in transparent clay

Huayang LEI, Yajie ZHANG, Yao HU, Yingnan LIU

《结构与土木工程前沿(英文)》 2021年 第15卷 第1期   页码 147-166 doi: 10.1007/s11709-020-0704-6

摘要: The stability of the shield tunneling face is an extremely important factor affecting the safety of tunnel construction. In this study, a transparent clay with properties similar to those of Tianjin clay is prepared and a new transparent clay model test apparatus is developed to overcome the “black box” problem in the traditional model test. The stability of the shield tunneling face (failure mode, influence range, support force, and surface settlement) is investigated in transparent clay under active failure. A series of transparent clay model tests is performed to investigate the active failure mode, influence range, and support force of the shield tunneling face under different burial depth conditions, whereas particle flow code three-dimensional numerical simulations are conducted to verify the failure mode of the shield tunneling face and surface settlement along the transverse section under different burial depth conditions. The results show that the engineering characteristics of transparent clay are similar to those of soft clay in Binhai, Tianjin and satisfy visibility requirements. Two types of failure modes are obtained: the overall failure mode (cover/diameter: / ≤1.0) and local failure mode ( / ≥2.0). The influence range of the transverse section is wider than that of the longitudinal section when / ≥2.0. Additionally, the normalized thresholds of the relative displacement and support force ratio are 3%–6% and 0.2–0.4, respectively. Owing to the cushioning effect of the clay layer, the surface settlement is significantly reduced as the tunnel burial depth increases.

关键词: shield tunneling face     stability     transparent clay     model test     numerical simulation    

Investigation of Generalized SIFs of cracks in 3D piezoelectric media under various crack-face conditions

Jaroon RUNGAMORNRAT, Bounsana CHANSAVANG, Weeraporn PHONGTINNABOOT, Chung Nguyen VAN

《结构与土木工程前沿(英文)》 2020年 第14卷 第2期   页码 280-298 doi: 10.1007/s11709-019-0586-7

摘要: This paper investigates the influence of crack geometry, crack-face and loading conditions, and the permittivity of a medium inside the crack gap on intensity factors of planar and non-planar cracks in linear piezoelectric media. A weakly singular boundary integral equation method together with the near-front approximation is adopted to accurately determine the intensity factors. Obtained results indicate that the non-flat crack surface, the electric field, and the permittivity of a medium inside the crack gap play a crucial role on the behavior of intensity factors. The mode-I stress intensity factors ( ) for two representative non-planar cracks under different crack-face conditions are found significantly different and they possess both upper and lower bounds. In addition, for impermeable and semi-permeable non-planar cracks treated depends strongly on the electric field whereas those of impermeable, permeable, and semi-permeable penny-shaped cracks are identical and independent of the electric field. The stress/electric intensity factors predicted by permeable and energetically consistent models are, respectively, independent of and dependent on the electric field for the penny-shaped crack and the two representative non-planar cracks. Also, the permittivity of a medium inside the crack gap strongly affects the intensity factors for all crack configurations considered except for of the semi-permeable penny-shaped crack.

关键词: crack-face conditions     intensity factors     non-flat cracks     permittivity     piezoelectric media     SGBEM    

lithology identification using multi-scale dilated convolutional attention network based on tunnel face

《结构与土木工程前沿(英文)》 2023年 第17卷 第12期   页码 1796-1812 doi: 10.1007/s11709-023-0002-1

摘要: For real-time classification of rock-masses in hard-rock tunnels, quick determination of the rock lithology on the tunnel face during construction is essential. Motivated by current breakthroughs in artificial intelligence technology in machine vision, a new automatic detection approach for classifying tunnel lithology based on tunnel face images was developed. The method benefits from residual learning for training a deep convolutional neural network (DCNN), and a multi-scale dilated convolutional attention block is proposed. The block with different dilation rates can provide various receptive fields, and thus it can extract multi-scale features. Moreover, the attention mechanism is utilized to select the salient features adaptively and further improve the performance of the model. In this study, an initial image data set made up of photographs of tunnel faces consisting of basalt, granite, siltstone, and tuff was first collected. After classifying and enhancing the training, validation, and testing data sets, a new image data set was generated. A comparison of the experimental findings demonstrated that the suggested approach outperforms previous classifiers in terms of various indicators, including accuracy, precision, recall, F1-score, and computing time. Finally, a visualization analysis was performed to explain the process of the network in the classification of tunnel lithology through feature extraction. Overall, this study demonstrates the potential of using artificial intelligence methods for in situ rock lithology classification utilizing geological images of the tunnel face.

关键词: hard-rock tunnel face     intelligent lithology identification     multi-scale dilated convolutional attention network     image classification     deep learning    

高混凝土面板堆石坝设计新理念

郦能惠

《中国工程科学》 2011年 第13卷 第3期   页码 12-18

摘要:

在分析混凝土面板堆石坝40多年经验设计及其不完全性的基础上,提出了高混凝土面板堆石坝设计新理念,即针对坝址的地形地质条件与料源情况,进行稳定安全设计、渗流安全设计和变形安全设计,阐述了稳定、渗流、变形安全设计的原则和要点,强调了变形协调原则和理论指导设计的重要性。

关键词: 混凝土面板堆石坝     设计新理念     稳定安全     渗流安全     变形安全    

Exploration of interconnected factory mode: Haier Jiaozhou Air Conditioner Interconnected Factory

Yunjie ZHOU

《工程管理前沿(英文)》 2017年 第4卷 第4期   页码 500-503 doi: 10.15302/J-FEM-2017105

关键词: interconnected factory mode     user-centered     mass customization     interconnection    

标题 作者 时间 类型 操作

Modeling of ion conductivity in Nafion membranes

YANG Zhen, PENG Xiaofeng, WANG Buxuan, DUAN Yuanyuan, LEE Duujong

期刊论文

Statistical modeling of radiolytic (

G. S. Muthu Iswarya, B. Nirkayani, A. Kavithakani, V. C. Padmanaban

期刊论文

Strengthening of the concrete face slabs of dams using sprayable strain-hardening fiber-reinforced cementitious

期刊论文

Effect of cutterhead configuration on tunnel face stability during shield machine maintenance outages

期刊论文

Method for solving the nonlinear inverse problem in gas face seal diagnosis based on surrogate models

期刊论文

Experimental study of face passive failure features of a shallow shield tunnel in coastal backfill sand

期刊论文

Real-time prediction of tunnel face conditions using XGBoost Random Forest algorithm

期刊论文

Dynamic in-plane transversal normal stresses in the concrete face of CFRD

Neftalí SARMIENTO-SOLANO, Miguel P. ROMO

期刊论文

Local uncorrelated local discriminant embedding for face recognition

Xiao-hu MA,Meng YANG,Zhao ZHANG

期刊论文

In-plane transversal normal stresses in the concrete face of CFRD induced by the first-dam reservoir

Neftalí SARMIENTO-SOLANO, Miguel P. ROMO

期刊论文

Model test and discrete element method simulation of shield tunneling face stability in transparent clay

Huayang LEI, Yajie ZHANG, Yao HU, Yingnan LIU

期刊论文

Investigation of Generalized SIFs of cracks in 3D piezoelectric media under various crack-face conditions

Jaroon RUNGAMORNRAT, Bounsana CHANSAVANG, Weeraporn PHONGTINNABOOT, Chung Nguyen VAN

期刊论文

lithology identification using multi-scale dilated convolutional attention network based on tunnel face

期刊论文

高混凝土面板堆石坝设计新理念

郦能惠

期刊论文

Exploration of interconnected factory mode: Haier Jiaozhou Air Conditioner Interconnected Factory

Yunjie ZHOU

期刊论文