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光催化 2

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K波段；高效率；宽带；氮化镓（GaN）；功率放大器 1

N3_C空位 1

“彩虹”捕获 1

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17–26.5 GHz 42.5 dBm宽带高效率GaN功率放大器设计 Correspondences

黎明1,2,李智群1,3,郑权2,蔺兰峰2,陶洪琪2

《信息与电子工程前沿（英文）》 2022年第23卷第2期页码 346-350 doi: 10.1631/FITEE.2000513

摘要：提出一种在微波频段具有宽带、高效率的氮化镓（GaN）功率放大器。该功率放大器采用0.15 μm栅长GaN-HEMT工艺，其工作频段可以覆盖整个K频段，即17–26.5 GHz。

关键词： K波段；高效率；宽带；氮化镓（GaN）；功率放大器

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温度对碳热还原/氮化法合成氮化硅的影响

万小涵,张广清,Oleg Ostrovski,Hal Aral

《中国工程科学》 2015年第17卷第1期页码 62-66

摘要：

碳热还原/氮化合成Si3N4在1 300～1 600 ℃下N2或N2-H2混合气中进行。反应物由非晶SiO2与C粉以1∶4.5摩尔比混合、压片。碳热还原/氮化法合成氮化硅的原理需进一步探讨。

关键词：碳热还原/氮化法；临界温度；生成物选择性；CO平衡分压

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石墨相氮化碳负载杂多酸——水相中高效光氧化苯甲醇 Article

吴立夫, 安赛, 宋宇飞

《工程（英文）》 2021年第7卷第1期页码 94-102 doi: 10.1016/j.eng.2020.07.025

摘要：在本文中，我们通过在磷酸功能化的石墨相氮化碳（g-C₃N₄）纳米片上负载磷钨酸成功制备了新型光催化剂（PW₁₂-P-UCNS，其中，PW12为H₃PW₁₂O₄₀·xH₂O，P-UCNS为磷酸修饰的超薄石墨相氮化碳

关键词：光催化杂多酸石墨相氮化碳苯甲醛

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III族氮化物材料和设备的未来技术及用途

Shuji Nakamura

《工程（英文）》 2015年第1卷第2期页码 161-161 doi: 10.15302/J-ENG-2015059

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Effect of extrusion temperature on the physical properties of high-silicon aluminum alloy

YANG Fuliang, GAN Weiping, CHEN Zhaoke

《机械工程前沿（英文）》 2007年第2卷第1期页码 120-124 doi: 10.1007/s11465-007-0021-y

摘要： Light-weight high-silicon aluminum alloys are used for electronic packaging in the aviation and space-flight industry. Al-30Si and Al-40Si are fabricated with air-atomization and vacuum-canning hot-extrusion process. The density, thermal conductivity, hermeticity and thermal expansion coefficients of the material are measured, and the relationship between extrusion temperature and properties is obtained. Experimental results show that the density of high-silicon aluminum alloys prepared with this method is as high as 99.64% of the theory density, and increases with elevating extrusion temperature. At the same time, thermal conductivity varies between 104-140 W/(m " K); with the extrusion temperature, thermal expansion coefficient also increases but within 13?10 (at 100?C) and hermeticity of the material is high to 10 order of magnitude.

关键词： coefficient hermeticity temperature relationship air-atomization

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Development, applications and challenges of ReaxFF reactive force field in molecular simulations

You Han, Dandan Jiang, Jinli Zhang, Wei Li, Zhongxue Gan, Junjie Gu

《化学科学与工程前沿（英文）》 2016年第10卷第1期页码 16-38 doi: 10.1007/s11705-015-1545-z

摘要： As an advanced and new technology in molecular simulation fields, ReaxFF reactive force field has been developed and widely applied during the last two decades. ReaxFF bridges the gap between quantum chemistry (QC) and non-reactive empirical force field based molecular simulation methods, and aims to provide a transferable potential which can describe many chemical reactions with bond formation and breaking. This review presents an overview of the development and applications of ReaxFF reactive force field in the fields of reaction processes, biology and materials, including (1) the mechanism studies of organic reactions under extreme conditions (like high temperatures and pressures) related with high-energy materials, hydrocarbons and coals, (2) the structural properties of nanomaterials such as graphene oxides, carbon nanotubes, silicon nanowires and metal nanoparticles, (3) interfacial interactions of solid-solid, solid-liquid and biological/inorganic surfaces, (4) the catalytic mechanisms of many types of metals and metal oxides, and (5) electrochemical mechanisms of fuel cells and lithium batteries. The limitations and challenges of ReaxFF reactive force field are also mentioned in this review, which will shed light on its future applications to a wider range of chemical environments.

关键词： ReaxFF reaction mechanism nanomaterials interfacial interaction catalyst fuel cell

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Electrochemical performance of thermally-grown SiO

GAN, Q. A. HUANG, J. Z. YANG

《能源前沿（英文）》 2018年第12卷第2期页码 225-232 doi: 10.1007/s11708-018-0556-0

摘要： Direct integration of lithium-ion battery (LIB) with electronic devices on the same Si substrate can significantly miniaturize autonomous micro systems. For achieving direct integration, a barrier layer is essential to be inserted between LIB and the substrate for blocking Li diffusion. In this paper, the feasibility of thermal SiO film as the barrier layer is investigated by electrochemical characterization and X-ray photoelectron spectroscopy (XPS). Due to the negligible side reactions of thermal SiO with electrolyte, the solid electrolyte interphase (SEI) layer formed on the surface of the barrier layer is thin and the SEI content mainly consists of hydrocarbon together with slight polyethylene oxide (PEO), Li PO F , and Li CO . Although 8-nm thermal SiO effectively prevents the substrate from alloying with Li , the whole film changes to Li silicate after electrochemical cycling due to the irreversible chemical reactions of SiO with electrolyte. This degrades the performance of the barrier layer against the electrolyte penetration, thus leading to the existence of Li (in the form of F-Si-Li) and solvent decompositions (with the products of hydrocarbon and PEO) near the barrier layer/substrate interface. Moreover, it is found that the reaction kinetics of thermal SiO with electrolyte decrease significantly with increasing the SiO thickness and no reactions are found in the bulk of the 30-nm SiO film. Therefore, thermal SiO with an appropriate thickness is a promising barrier layer for direct integration.

关键词： autonomous micro system direct integration barrier layer thermal SiO₂ film X-ray photoelectron spectroscopy (XPS)

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Cation exchange resin supported nanoscale zero-valent iron for removal of phosphorus in rainwater runoff

XIE Bangmi,ZUO Jiane,GAN Lili,LIU Fenglin,WANG Kaijun

《环境科学与工程前沿（英文）》 2014年第8卷第3期页码 463-470 doi: 10.1007/s11783-013-0575-3

摘要： Self-made cation exchange resin supported nanoscale zero-valent iron (R-nZVI) was used to remove phosphorus in rainwater runoff. 80% of phosphorus in rainwater runoff from grassland was removed with an initial concentration of 0.72 mg·L phosphorus when the dosage of R-nZVI is 8 g per liter rainwater, while only 26% of phosphorus was removed when using cation exchange resin without supported nanoscale zero-valent iron under the same condition. The adsorption capacity of R-nZVI increased up to 185 times of that of the cation exchange resin at a saturated equilibrium phosphorous concentration of 0.42 mg·L . Various techniques were implemented to characterize the R-nZVI and explore the mechanism of its removal of phosphate. Scanning electron microscopy (SEM) indicated that new crystal had been formed on the surface of R-nZVI. The result from inductive coupled plasma (ICP) indicated that 2.1% of nZVI was loaded on the support material. The specific surface area was increased after the load of nanoscale zero-valent iron (nZVI), according to the measurement of BET-N method. The result of specific surface area analysis also proved that phosphorus was removed mainly through chemical adsorption process. X-ray photoelectron spectroscopy (XPS) analysis showed that the new product obtained from chemical reaction between phosphate and iron was ferrous phosphate.

关键词： nanoscale zero-valent iron(R-nZVI) cation exchange resin rainwater runoff phosphorus adsorption

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余弦忆导忆阻系统周期变化初值位移调控行为 Regular Papers

Mo CHEN, Xue REN, Hua-gan WU, Quan XU, Bo-cheng BAO

《信息与电子工程前沿（英文）》 2019年第20卷第12期页码 1706-1716 doi: 10.1631/FITEE.1900360

摘要：利用一种新型余弦忆导理想忆阻，构造一个四维忆阻系统。由于忆导函数特殊的非线性，忆阻系统具有沿忆阻内部状态变量坐标轴分布的线平衡点集(0, 0, 0, δ)，且平衡点集稳定性随δ变化而周期性演化。数值仿真揭示了忆阻系统非线性、一维的初值位移调控行为，它不仅可由忆阻状态初值触发，也可由其他两个系统状态初值引发。特别地，在位移调控路线上，可以观测到多种具有不同位置和拓扑结构的共存吸引子。通过PSIM电路仿真对该特殊动力学特性进行了验证。

关键词：初值位移调控；忆阻系统；忆导；线平衡点集

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Comprehensive health condition assessment on partial sewers in a southern Chinese city based on fuzzy mathematic methods

Lili GAN, Jiane ZUO, Yajiao WANG, Thong Soon LOW, Kaijun WANG

《环境科学与工程前沿（英文）》 2014年第8卷第1期页码 144-150 doi: 10.1007/s11783-013-0554-8

摘要： A self-developed sewer health assessment system using the fuzzy comprehensive evaluation and analytical hierarchy process was applied to give a comprehensive health condition evaluation on part of the local sewers in a southern Chinese city based on the sewer video data collected by a sewer inspection closed circuit television (CCTV) robot. Aside from the overall condition evaluation, the structure, function, and stability status of the sewer were also analyzed using the method. A comprehensive index was proposed to give the overall health condition of pipes with different defects, and , , and were used to quantify the defects affecting the tightness, stability, and function of the pipe, respectively. Results show that 48% of the inspected pipes were in good condition (0< <0.25), and about 33% of the sewer pipes analyzed were categorized to be at severe or urgent condition levels ( >0.5), although most of the pipes were installed only within five years. Frequent sedimentation affects the function of the sewer, and deformation and joint damage affect the structure of the sewer.

关键词： sewer health condition assessment analytical hierarchy process fuzzy comprehensive evaluation fuzzy mathematic method

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过硫酸盐诱导的缺陷氮化碳中三配位氮（N3_C）空位增强光催化产过氧化氢 Article

缪蔚, 王奕杰, 刘莹, 秦贺贺, 褚成成, 毛舜

《工程（英文）》 2023年第25卷第6期页码 214-221 doi: 10.1016/j.eng.2021.12.016

摘要：其中石墨氮化碳（g-C₃N₄）被认为是最有前途的合成过氧化氢的光催化剂之一；并且，在g-C₃N₄中引入氮空位已被证明是提高其光催化活性的有效策略

关键词：氮化碳 N3_C空位过氧化氢光催化过硫酸盐

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FAST——500米口径球面射电望远镜

Peng Jiang, Hengqian Gan, Rui Yao, Jinghai Sun, Jiguang Lu, Dongjun Yu, Hui Li, Jinglong Yu, Bin Dong

《工程（英文）》 2023年第28卷第9期页码 21-25 doi: 10.1016/j.eng.2023.04.001

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Bioinspired C/TiO

Jian LI, Likun GAO, Wentao GAN

《农业科学与工程前沿（英文）》 2017年第4卷第4期页码 459-464 doi: 10.15302/J-FASE-2017178

摘要： butterfly wings were replicated by a sol-gel method and a calcination process, which could take advantage of the spatial features of the wing to enhance their photocatalytic properties. Hierarchical structures of -carbon-TiO (PP-C-TiO ) were confirmed by SEM observations. By applying the Brunauer-Emmett-Teller method, it was concluded that in the presence of wings the product shows higher surface area with respect to the pure TiO made in the absence of the wings. The higher specific surface area is also beneficial for the improvement of photocatalytic property. Furthermore, the conduction and valence bands of the PP-C-TiO are more negative than the corresponding bands of pure TiO , allowing the electrons to migrate from the valence band to the conduction band upon absorbing visible light. That is, the presence of C originating from wings in the PP-C-TiO could extend the photoresponsiveness to visible light. This strategy provides a simple method to fabricate a high-performance photocatalyst, which enables the simultaneous control of the morphology and carbon element doping.

关键词： bioinspired butterfly wings C/TiO₂ photocatalyst visible light