[ 1 ] Singhal S C，Kendall K. High Temperature Solid Oxide Fuel Cells：Fundamentals，Design，and Applications [M]. Amsterdam：Elsevier，2003.

[ 2 ] Atkinson A，Barnett S，Gorte R J，et al. Advanced anodes for high-temperature fuel cells [J]. Nat Mater，2004，3：17-27. link1

[ 3 ] Mclntosh S，Gorte R J. Direct hydrocarbon solid oxide fuel cells [J]. Chem Rev，2004，104 ：4845-4865. link1

[ 4 ] Jiang S P，Chan S H. A review of anode materials development in solid oxide fuel cells [J]. J Mater Sci，2004，39：4405-4439. link1

[ 5 ] Mogensen M，Kammer K. Conversion of hydrocarbons in solid oxide fuel cells [J]. Annu Rev Mater Res，2003，33：321-331. link1

[ 6 ] Fergus J W. Oxide anode materials for solid oxide fuel cells [J]. Solid State Ionics，2006，177：1529-1541.

[ 7 ] Sun C W，Stimming U. Recent anode advances in solid oxide fuel cells [J]. J Power Sources，2007，171：247-260. link1

[ 8 ] Lashtabeg A，Skinner S J. Solid oxide fuel cells- a challenge for materials chemists? [J] J Mater Chem，2006，16：3160-3170. link1

[ 9 ] Fuel Cell Handbook，7th ed.，US Department of Energy，Morgantown，WV，2004，www.netl.doe.gov [EB/OL]. link1

[10] Gorte R J，Vohs J M. Novel SOFC anodes for the direct electrochemicaloxidationofhydrocarbons [J].JCatal，2003，216：477-486. link1

[11] Brown M，Primdahl S，Mogensen M. Structure/performance relations for Ni/ytrria-stabilized zirconia anodes for solid oxide fuel cells [J]. J Electrochem Soc，2000，147：475-485.

[12] Tanner C W，Fung K Z，Virkar A V. The effect of porous composite electrode structure on solid oxide fuel cell performance. 1. Theoretical analysis [J]. J Electrochem Soc，1997，144：21-30.

[13] Wilson J R，Kobsiriphat W，Mendoza R，et al. Three- dimensional reconstruction of a solid-oxide fuel-cell anode，Nat. Mater，2006，5：541-544. link1

[14] Brandon N P，Skinner S，Steele B C H. Recent advances in materials for fuel cells [J]. Annu Rev Mater Res，2003，33：183-213. link1

[15] Suzuki T，Hasan Z，Funahashi Y，et al. Impact of anode microstructure on solid oxide fuel cells [J]. Science，2009，325：852-855. link1

[16] Minh N Q. Ceramic fuel-cells [J]. J Am Ceram Soc，1993，76： 563-588. link1

[17] Zhu W Z，Deevi S C. A review on the status of anode materials for solid oxide fuel cells [J]. Mater Sci Eng，A2003，362：228-239. link1

[18] Steele B C H. Appraisal of Ce1- yGdyO2- y/2 electrolytes for ITSOFC operation at500℃[J]. Solid State Ionics，2000，129：95-110. link1

[19] Murray E P，Tsai T，Barnett S A. A direct- methane fuel cell with a ceria-based anode [J]. Nature，1999，400：649-651. link1

[20] Park S，Vohs J M，Gorte R J. Direct oxidation of hydrocarbons in a solid-oxide fuel cell [J]. Nature，2000，404：265-267. link1

[21] McIntosh S，Vohs J M，Gorte R J. Role of hydrocarbon deposits in the enhanced performance of direct-oxidation SOFCs [J]. J Electrochem Soc，2003，150：A470-A476.

[22] Kim H，Lu C，Worrell W L，et al. Cu-Ni ceramet anodes for direct oxidation of methane in solid-oxide fuel cells [J]. J Electrochem Soc，2002，149：A247-A250.

[23] Lee S，Vohs J M，Gorte R J. A study of SOFC anodes based on Cu-Ni and Cu-Co bimetallics in CeO2-YSZ [J]. J Electrochem. Soc，2004，151：A1319-A1323.

[24] Xie Z，Zhu W，Zhu B，et al. FexCo0.5-x-SDC anodes for low-temperature solid oxide fuel cells [J]. Electrochim Acta，2006，51： 3052-3057. link1

[25] Sun C W，Sun J，Xiao G L，et al. Mesoscale organization of nearly monodisperse flowerlike ceria microspheres [J]. J Phys Chem B，2006，110：13445-13452. link1

[26] Skorodumova N V，Simak S I，Lundqvist B I，et al. Quantum origin of the oxygen storage capability of ceria [J]. Phys Rev Lett，2002，89：166601. link1

[27] Marina O A，Mogensen M. High- temperature conversion of methane on a composite gadolinia- doped ceria- gold electrode [J]. Appl Catal A，1999，189：117-126. link1

[28] Saeki M J，Uchida H，Watanabe M. Nobel metal catalysts highly-dispersed on Sm-doped ceria for the application to internal reforming solid oxide fuel cells operated at medium temperature [J]. Catal Lett，1994，26：149-157. link1

[29] Hibino T，Hashimoto A，Yano M，et al. Ru- catalyzed anode materials for direct hydrocarbon SOFCs [J]. Electrochim Acta， 2003，48：2531-2537. link1

[30] Zhan Z，Barnett S A. An octane-fueled solid oxide fuel cell [J]. Science，2005，308：844-847. link1

[31] Sun C W，Xie Z，Xia C R，et al. Invesitigations of mesoporous CeO2-Ru as a reforming catalyst layer for solid oxide fuel cells [J]. Electrochem Commun，2006，8：833-838. link1

[32] Ramirez-Cabrera E，Atkinson A，Chadwick D. The influence of point defects on the resistance of ceria to carbon deposition in hydrocarbon catalysis [J]. Solid State Ionics，200，136：825-831. link1

[33] Antonucci V，Faro M L，Rosa D L. Proceedings International Hydrogen Energy Congress and Exhibition IHEC 2005 [C]// Turkey，Istanbul：2005.

[34] Wisniewski M，Boreave A，Gelin P. Catalytic CO2 reforming of methane over Ir/Ce0.9Gd0.1O2-x [J].CatalCommun，2005，6：596-600. link1

[35] Hibino T，Hashimoto A，Yano M，et al. High performance anodes for SOFCs operting in methane-air mixture at reduced temperatures [J]. J Electrochem Soc，2002，149：A133-A136.

[36] Ahn K，He H P，Vohs J M，et al. Enhanced thermal stability of SOFC anodes made with CeO2- ZrO2 solutions[J]. Electrochem Solid-State Lett，2005，8：A414-A417.

[37] Ye X F，Huang B，Wang S R，et al. Preparation and performance of a Cu-CeO2-ScSZ composite anode for SOFCs running on ethanol fuel[J]. J Power Sources，2007，164：203-209. link1

[38] Hirabayashi D，Hashimoto A，Hibino T，et al. Bi-based oxide anodes for direct hydrocarbon SOFCs at intermediate temperatures，Electrochem[J]. Solid-State Lett，2004，7：A108-A110.

[39] Yang L，Choi Y，Qin W，et al. Promotion of water-mediated carbon removal by nanostructured barium oxide/nickel interfaces in solid oxide fuel cells [J]. Nature Commun，2011，2. DOI： 10.1038/ncomms1359.

[40] Boukamp B A. The amazing perovskite anode [J]. Nat Mater， 2003，2：294-296. link1

[41] Tao S W，Irvine J T S. A redox-stable efficient anode for solid oxide fuel cells [J]. Nat Mater，2003，2：320-323. link1

[42] Zha S W，Tsang P，Cheng Z，et al. Electrical properties and sulfur tolerance of La0.75Sr0.25Cr1- xMnxO3 under anodic conditions [J]. J Solid State Chem，2005，178：1844-1850. link1

[43] Huang Y H，Dass R I，Denyszyn J C，et al. Synthesis and characterization of Sr2MgMoO6- δ [J]. J Electrochem Soc，2006，153： A1266-A1272.

[44] Huang Y H，Dass R I，Xing Z L，et al. Double perovskites as anode materials for solid- oxide fuel cells [J]. Science，2006， 312：254-257. link1

[45] Zhang P，Huang Y，Cheng J，et al. Sr2CoMoO6 anode for solid oxide fuel cell running on H2 and CH4 fuels [J]. J Power Sources，2011，196：1738-1743. link1

[46] Yang L，Wang S，Blinn K，et al.，Enhanced sulfur and coking tolerance of a mixed ion conductor for SOFCs：BaZr0.1Ce0.7Y0.2- x YbxO3-δ [J]. Science，2009，326：126-129.

[47] Vernoux P，Guillodo M，Fouletier J，et al. Alternative anode material for gradual methane reforming in solid oxide fuel cells [J]. Solid State Ionics，2000，135：425-431. link1

[48] Sauvet A L，Fouletier J. Electrochemical properties of a new type of anode material La1-xSrxCr1-yRuyO3-δ for SOFC under hydrogen and methane at intermediate temperatures [J]. Electrochim Acta，2001，47：987-995. link1

[49] Sauvet A L，Fouletier J，Gaillard F，et al. Surface properties and physicochemical characterizations of a new type of anode material，La1- xSrxCr1- yRuyO3- δ，for a solid oxide fuel cell under methane at intermediate temperature [J]. J Catal，2002，209：25-34. link1

[50] Sauvet A L，Irvine J T S A. Catalytic activity for steam methane reforming and physical characterization of La1-xSrxCr1-yNiyO3-δ [J]. Solid State Ionics，2004，167：1-8. link1

[51] Liu J，Madsen B D，Ji Z Q，et al. A fuel- flexible ceramicbased anode for solid oxide fuel cells [J]. Electrochem SolidState Lett，2002，5：A122-A124.

[52] Chen X J，Liu Q L，Khor K A，et al. High-performance (La，Sr) (Cr，Mn)O3/(Gd，Ce)O2-δ composite anode for direct oxidation of methane [J]. J Power Sources，2007，165：34-40. link1

[53] Jiang S P， Chen X J，Chan S H，et al. GDC- impregnated (La0.75Sr0.25)(Cr0.5Mn0.5)O3 anodes for direct utilization of methane in solid oxide fuel cells [J]. J Electrochem Soc，2006，153： A850-A856.

[54] Zhu X，Lv Z，Wei B，et al. Fabrication and performance of membrane solid oxide fuel cells with La0.75Sr0.25Cr0.5Mn0.5O3- δ impregnated anodes [J]. J Power Sources，2010，195：1793-1798. link1

[55] Jiang S P，Ye Y，HeT，et al. Nanostructured palladiumLa0.75Sr0.25Cr0.5Mn0.5O3/Y2O3- ZrO2 composite anodes for direct methane and ethanol solid oxide fuel cells [J]. J Power Sources， 2008，185：179-182. link1

[56] Sin A，Kopnin E，Dubitsky Y，et al. Antonucci，Stabilisation of composite LSFCO-CGO based anodes for methane oxidation in solid oxide fuel cells [J]. J Power Sources，2005，145：68-73. link1

[57] Faro M L，Rosa D L，Nicotera I，et al. Electrochemical behavior of propane- fed solid fuel cells based on low Ni content anode catalysts [J]. Electrochimica Acta，2009，54：5280-5285. link1

[58] Slater P R，Fagg D P，Irvine J T S. Synthesis and electrical characterization of doped perovskite titanates as potential anode materials for solid oxide fuel cells [J]. J Mater Chem，1997，7： 2495-2498. link1

[59] Mukundan R，Brosha E L，Garzon F H. Sulfur tolerant anodes for SOFCs [J]. Electrochem Solid-State Lett，2004，7：A5-A7.

[60] Balachandran U，Eror N G. Electrical conductivity in strontium titanate [J]. J Solid State Chem，1981，9：351-359. link1

[61] Kolodiazhnyi T，Petric A. The applicability of Sr- deficient ntype SrTiO3 for SOFC anodes [J]. JElectroceramics，2005，15：5-11. link1

[62] Marina O A，Canfield N L，Stevenson J W. Thermal，electrical，and electrocatalytical properties of lanthanum-doped strontium titanate [J]. Solid State Ionics，2002，149：21-28. link1

[63] Li X，Zhao H，Shen W，et al. Synthesis and properties of Ydoped SrTiO3 as an anode material for SOFCs [J]. J Power Sources，2007，166：47-52. link1

[64] Périllat-Merceroz C，Gauthier G，Roussel P，et al. Synthesis and study of a Ce-doped La/Sr titanate for solid oxide fuel cell anode operating directly on methane [J]. Chem Mater，2011，23： 1539-1550. link1

[65] Hui S，Petric A. Evaluation of yttrium-doped SrTiO3 as an anode for solid oxide fuel cells [J]. J Eur Ceram Soc，20023，22： 1673-1681. link1

[66] Vernoux P，Djurado E，Guillodo M. Catalytic and electrochemical properties of doped lanthanum chromites as new anode materials for solid oxide fuel cells [J]. J Am Ceram Soc，2001，84： 2289-2295. link1

[67] Ruiz-Morales J C，Canales-vazqzez J，Savaniu C，et al. Disruption of extended defects in solid oxide fuel cell anodes for methane oxidation [J]. Nature，2006，439：568-571. link1

[68] Bastidas D M，Tao S W，Irvine J T S. A symmetrical solid oxide fuel cell demonstrating redox stable perovskite electrodes [J]. J Mater Chem，2006，16：1603-1605. link1

[69] Liu Q，Dong X，Xiao G，et al. A novel electrode material for symmetrical SOFCs [J]. Adv Mater，2010，22：5478-5482. link1

[70] Ruiz-Morales J C，Canales-Vazquez J，Pena-Martinez J，et al. On the simultaneous use of La0.75Sr0.25Cr0.5Mn0.5O3-δ as both anode and cathode material with improved microstructure in solid oxide fuel cells [J]. Electrochim Acta，2006，52：278-284. link1

[71] Yang C，Yang Z，Jin C，et al. Sulfur-tolerant redox- reversible anode material for direct hydrocarbon solid oxide fuel cells [J]. Adv Mater，2012，24：1439-1443. link1

[72] Matsuzaki Y，Yasuda I. The poisoning effect of sulfur-containing impurity gas on a SOFC anode：Part I. Dependence on temperature，time，and impurity concentration [J]. Solid State Ionics，2000，132：261-269. link1

[73] Wang S Z，Liu M L，Winnick J. Stabilities and electrical conductivities of electrode materials for use in H2S-containing gases [J]. J Solid State Electrochem，2001，5：188-195. link1

[74] He H P，Gorte R J，Vohs J M. Highly sulfur tolerant Cu-ceria anodes for SOFCs [J]. Electrochem Solid- State Lett，2005，8： A279-A280. link1

[75] Kurokawa H，Sholklapper T Z，Jacobson C P，et al. Ceria nanocoating for sulfur tolerant Ni- based anodes of solid oxide fuel cells [J]. Electrochem Solid State Lett，2007，10：B135-B138.

[76] Mukundan R，Brosha E L，Garzon F H. Sulfur tolerant anodes for SOFCs [J]. Electrochem Solid-State Lett，2004，7：A5-A7.

[77] Lu X C，Zhu J H，Yang Z G，et al. Pd-impregnated SYT/LDC composite as sulfur-tolerant anode for solid oxide fuel cells [J]. J Power Sources，2009，192：381-384. link1

[78] Kurokawa H，Yang L，Jacobson C P，et al. Y- doped SrTiO3 based sulfur tolerant anode for solid oxide fuel cells [J]. J Power Sources，2007，164：510-518. link1

[79] Zha S W，Cheng Z，Liu M L. A sulfur-tolerant anode material for SOFCs [J]. Electrochem Solid-State Lett，2005，8：A406-A408.

[80] Flytzani-Stephanopoulos M，Sakbodin M，Wang Z. Regenerative adsorption and removal of H2S from hot fuel gas streams by rare earth oxides [J]. Science，2006，312：1508-1510. link1