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Strategic Study of CAE >> 2013, Volume 15, Issue 2

Prospect of carbon-based solid oxide fuel cells

Union Research Center of Fuel Cell, School of Chemical and Environmental Engineering, State Key Laboratory of Coal Resoures and Safe Mining, China University of Mining & Technology, Beijing 100083, China

Funding project:国家重点基础研究发展计划“973计划”资助项目(2012CB215404);国家自然科学基金资助项目(51110463) Received: 2012-11-30 Available online: 2013-01-28 10:49:15.000

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Abstract

Fossil fuel such as coal, oil and nature gas is the main energy resource in China even in the world. It has low power generation efficiency (approximately 30 %) and a great environmental impact, which needs to be improved. The fuel cell which could turn chemical energy directly into electrical energy is a kind of high efficiency power generation device (50 %~60 %). In all kinds of fuel cells, solid oxide fuel cell (SOFC) could use many kinds of carbon-based fuels which could be easily compatible with the existed energy resource supply system and has high power generation efficiency. All solid structures are adopted in SOFC system and excellent long term stability is observed during operation when using this kind of fuel cell. Low cost is obtained because no precious metal catalyst is used in SOFC. SOFC is especially suitable for distributed generation system and power supply system. Because of the energy structure and the superiority of rare earth resource in China, it is necessary to develop carbon-based SOFC. Improving long term stability and reducing costs are needed in the process from model operation to industrialization of SOFC. Several techniques of the carbon-based SOFC need to be focused on in the future, such as key materials, innovation by systematic integration, design and preparation of material, reaction characteristics of carbon-based fuels, cell structure, theoretical modeling and the problems of foundation science and technique in SOFC integration and operation. The measures above establish the foundation of industrialization for high efficiency, low cost and reliable carbon-based SOFC system.

References

[ 1 ] Zhan Z L ,Barnett S A. An octane-fueled solid oxide fuel cell[J]. Science,2005,308:844-847. link1

[ 2 ] Sun C W,Xie Z,Xia C R,et al. Investigations of mesoporous CeO2-Ru as a reforming catalyst layer for solid oxide fuel cells [J]. Electrochemistry Communications,2006,8 (5):833-838. link1

[ 3 ] Ding D,Liu Z B,Li L,et al. An octance- fueled low temperature solid oxide fuel with Ru- free anodes[J].Electrochemistry Communications,2008,10:1295-1298. link1

[ 4 ] Cao D X,Sun Y,Wang G L. Direct carbon fuel cell:Fundamentals and recent developments[J]. Journal of Power Sources, 2007,167:250-257. link1

[ 5 ] Gür T M. Coal conversion in a Fluidized Bed Direct Carbon Fuel Cell[C]//10th Annual Solid State Energy Conversion Alliance (SECA) Workshop,Pittsburg,2009.

[ 6 ] Yin Y H,Zhu W,Xia C R,et al. Low-temperature SOFCs using biomass- produced gases as fuels[J]. Journal of Applied Electrochemistry,2004,34 (12):1287-1291. link1

[ 7 ] 国家高技术研究发展计划(十一五863计划)先进能源技术领 域专家组.中国先进能源技术发展概论[M]. 北京:中国石油出 版社,2010.

[ 8 ] Han Minfang ,Zhou Su,Liu Ze,et al. Fabrication,sintering and electrical properties of cobalt oxide doped Gd0.1Ce0.9O2 − δ[J]. Solid State Ionics,2011,192:181-184. link1

[ 9 ] Zha S W,Xia C R,Meng G Y. Effect of Gd (Sm) doping on properties of ceria electrolyte for solid oxide fuel cells[J]. J.Power Sources,2003,115:44-48. link1

[10] Steele B C H. Appraisal of Ce1- yGdyO2- y/2 electrolytes for ITSOFC operation at 500 degrees [J]. Solid State Ionics,2000, 129(1-4):95-110. link1

[11] Liu Y,Zha S,Liu M. Novel nanostructured electrodes for solid oxide fuel cells fabricated by combustion chemical vapor deposition (CVD) [J]. Advanced Materials (Weinheim,Germany), 2004,16(3):256-260. link1

[12] Ishihara T,Matsuda H,Takita Y. Doped LaGaO3 perovskite type oxide as a new oxide ionic conductor[J]. J. Am. Chem. Soc.,1994,116(9):3801-3803. link1

[13] Huang K Q,Feng M,Goodenough J B. Sol-gel synthesis of a new oxide-ion conductor Sr-and Mg-doped LaGaO3 perovskite [J]. Journal of the American Ceramic Society,1997,79(4): 1100-1104. link1

[14] Xie Z,Xia C R,Zhang M Y,et al. Ni1-xCux alloy-based anodes for low-temperature solid oxide fuel cells with biomass-produced gas as fuel[J].Journal of power sources,2006,161(2):1056-1061. link1

[15] Tao S W,Irvine J T S. A redox-stable efficient anode for solidoxide fuel cells[J]. Nature Materials,2003,2(5):320-323. link1

[16] Park S D,Vohs J M,Gorte R J. Direct oxidation of hydrocarbons in a solid-oxide fuel cell[J]. Nature,2000,404:265-267. link1

[17] Yang L,Wang S,Blinn K,et al. Enhanced sulfur and coking tolerance of a mixed ion conductor for SOFCs:BaZr0.1Ce0.7Y0.2- x YbxO3-d[J]. Science,2009(10):126-129.

[18] 辛格哈尔. 高温固体氧化物燃料电池——原理、设计和应用 [M]. 韩敏芳,蒋先锋,译. 北京:科学出版社,2007.

[19] 彭苏萍,韩敏芳. 煤基/碳基固体氧化物燃料电池技术发展 前沿[J]. 自然杂志(特约稿),2009,31(4):187-192. link1

[20] 韩敏芳,彭苏萍. 固体氧化物燃料电池材料及制备[M]. 北京: 科学出版社,2004.

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