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Automated retrofit targeting of heat exchanger networks

Timothy G. Walmsley, Nathan S. Lal, Petar S. Varbanov, Jiří J. Klemeš

《化学科学与工程前沿（英文）》 2018年第12卷第4期页码 630-642 doi: 10.1007/s11705-018-1747-2

摘要：

The aim of this paper is to develop a novel heat exchanger network (HEN) retrofit method based on a new automated retrofit targeting (ART) algorithm. ART uses the heat surplus-deficit table (HSDT) in combination with the Bridge Retrofit concepts to generate retrofit bridges option, from which a retrofit design may be formulated. The HSDT is a tabular tool that shows potential for improved re-integration of heat source and sink streams within a HEN. Using the HSDT, retrofit bridges—a set of modifications that links a cooler to a heater to save energy—may be identified, quantified, and compared. The novel retrofit method including the ART algorithm has been successfully implemented in Microsoft Excel^TM to enable analysis of large-scale HENs. A refinery case study with 27 streams and 46 existing heat exchangers demonstrated the retrofit method’s potential. For the case study, the ART algorithm found 68903 feasible unique retrofit opportunities with a minimum 400 kW·unit⁻¹ threshold for heat recovery divided by the number of new units. The most promising retrofit project required 3 new heat exchanger units to achieve a heat savings of 4.24 MW with a favorable annualised profit and a reasonable payback period.

关键词： process retrofit pinch analysis heat exchanger network heat recovery

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Heat Integration retrofit analysis—an oil refinery case study by Retrofit Tracing Grid Diagram

Andreja NEMET, Jiří Jaromír KLEMEŠ, Petar Sabev VARBANOV, Valter MANTELLI

《化学科学与工程前沿（英文）》 2015年第9卷第2期页码 163-182 doi: 10.1007/s11705-015-1520-8

摘要： Heat Integration has been established over the last decades as a proven chemical engineering methodology. Two design implementations are often used in the industry: grassroots and retrofit. Although various methods have been developed for retrofit, it still needs more development to ensure simultaneously thermodynamic feasibility and economic viability. In this paper, a novel graphical approach has been developed to facilitate the understanding of the current situation and scope of improvement. The Retrofit Tracing Grid Diagram presents all streams and heat exchangers in temperature scale and the heat exchangers are clearly separated from each other, enabling clear visualisation of the current state. The tool incorporates the previously developed Cross-Pinch Analysis as well as path approach for retrofit. Additionally, the non-vertical heat transfer can be evaluated. The application of the developed tool has been validated on an oil refinery case study. The applicability of the tool is evident as it can reveal additional options for modification that none of the previous methods considered.

关键词： Heat Integration retrofit Pinch Analysis thermodynamic approach oil refinery

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Seismic retrofit of existing SRC frames using rocking walls and steel dampers

Akira WADA, Zhe QU, Shojiro MOTOYUI, Hiroyasu SAKATA

《结构与土木工程前沿（英文）》 2011年第5卷第3期页码 259-266 doi: 10.1007/s11709-011-0114-x

摘要： A retrofit of an existing 11-story steel reinforced concrete frame that features the innovative use of post-tensioned rocking walls and shear steel dampers is presented. The main components of the retrofitting plan and important design considerations are described. The retrofitting system is expected to effectively control the deformation pattern of the existing structure and significantly reduce damage to the existing structure during major earthquakes.

关键词： building structure seismic retrofit rocking wall steel damper

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既有居住建筑节能改造外部性及其量化研究

赵琰,刘晓君

《中国工程科学》 2014年第16卷第10期页码 100-105

摘要：

既有商品住宅节能改造具有一定程度的外部性，阻碍了节能改造的深入开展。通过分析节能改造外部性的产生原因和外部性表现，建立外部性测算方法，为外部性内部化，构建节能改造外部性偿还机制提供必要依据。采用经济学理论与方法对既有商品住宅节能改造外部性的产生和表现等进行了分析，在识别外部性供体与受体的基础上，提出了节能改造外部性的测算方法。通过案例分析论证了外部性测算方法的适用性。结果表明，应减轻或消除外部性对节能改造的影响，采取必要手段将节能改造外部性内部化，构建统一的节能改造外部性测算方法，建立节能改造外部性偿还与节能量交易机制。

关键词：既有商品住宅节能改造外部性测算

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Achieving energy efficiency in government buildings through mandatory policy and program enforcement

Patrick X.W. ZOU, Morshed ALAM, Van Manh PHUNG, Dipika WAGLE, Rodney STEWART, Edoardo BERTONE, Oz SAHIN, Chris BUNTINE

《工程管理前沿（英文）》 2017年第4卷第1期页码 92-103 doi: 10.15302/J-FEM-2017101

摘要： Government buildings are responsible for a significant proportion of energy consumption worldwide, for example, in Australia, up to 41.5 PJ energy was consumed by government buildings in 2011–2012. While the newly constructed buildings may be energy efficient, the existing buildings, which account for more than 85% of the total building stock, were built prior to the time when energy rating systems was put in practice and are consequently energy inefficient to a large degree. Reducing the energy consumption in existing government buildings is essential, as it will not only reduce the costs and environmental impacts, but also show governments’ strong commitment towards the reduction of greenhouse gas emission. Furthermore, successful building energy retrofit projects are the showcases to the general public, encouraging other sectors (e.g. commercial) to conduct building retrofits for energy savings. Recognising these benefits, several state governments in Australia have introduced building energy efficiency policies and programs. This paper reviewed the energy efficiency policies/programs in five States in Australia: Victoria, New South Wales, South Australia, Western Australia, and Queensland in terms of respective policies and targets, implementation methods and current progress. The lessons learned from these programs were also discussed. This research revealed that the key factors for a successful government building energy retrofitting program are 1) having a properly enforced energy efficiency mandate with clear energy saving targets, 2) establishing an expert facilitation team and 3) implementing suitable financing and procurement methods.

关键词： building energy retrofit policy energy efficiency energy performance contract energy auditing

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PBO纤维片材预应力外粘结加固集成新技术

吴智深,岩下健太郎,牛赫东

《中国工程科学》 2005年第7卷第9期页码 18-24

摘要：

近年采用外部粘结纤维增强复合材料(FRP)来加固结构越来越受到许多研究开发机构和生产单位的重视。结合作者在FRP方面的研究成果和最新开发出的高强高性能的PBO纤维材料，系统地提出了一种更为有效的预应力外粘结加固方法；通过与玻璃纤维、炭素纤维和芳纶纤维等的比较，认清了新型PBO纤维材料的特性；根据既有的试验和研究成果提出了一套完整的预应力加固方法的流程，包括概念、原理和几种降低端部界面应力和新型锚固的措施；室内小型试验和室外大型试验的结果表明，PBO片材预应力技术能够提供令人满意的加固性能。

关键词：纤维增强聚合物(FRP) PBO纤维片材增强加固外粘结锚固措施

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Applications of the crystallization process in the pharmaceutical industry

Sohrab ROHANI

《化学科学与工程前沿（英文）》 2010年第4卷第1期页码 2-9 doi: 10.1007/s11705-009-0297-z

摘要： The applications of the crystallization technique in the pharmaceutical industry as a purification and separation process for the isolation and synthesis of pure active pharmaceutical ingredients (API), co-crystals, controlled release pulmonary drug delivery, and separation of chiral isomers are briefly discussed using a few case studies. The effect of process variables and solvent on the polymorphism and morphology of stavudine is discussed. The implementation of external control in the form of feedback and real-time optimal control using cooling and antisolvent crystallization of paracetamol in water-isopropyl alcohol is introduced. Two methods to prepare micron-sized drug particles, namely, micro-crystallization and polymer-coated API-loaded magnetic nanoparticles for pulmonary drug delivery, are discussed. The significance of co-crystals in drug administration is highlighted using the theophylline-nicotinamide co-crystal system. Resolution of chloromandelic acid derivatives, a racemic compound, is achieved using direct crystallization and diastereomeric salts crystallization. The crystal structures of diastereomeric salts of chloromandelic acid and phenylethylamine are determined. The structure comparison between the less soluble and more soluble salts shows that weak interactions such as CH/π interactions and van der Waals forces contribute to chiral recognition when the hydrogen bonding patterns are similar.

关键词： feedback morphology pulmonary paracetamol recognition

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Degradation of refractory organics in concentrated leachate by the Fenton process: Central compositedesign for process optimization

Senem Yazici Guvenc, Gamze Varank

《环境科学与工程前沿（英文）》 2021年第15卷第1期 doi: 10.1007/s11783-020-1294-1

摘要： Abstract • 90% total COD, 95.3% inert COD and 97.2% UV254 were removed. • High R2 values (over 95%) for all responses were obtained with CCD. • Operational cost was calculated to be 0.238 €/g CODremoved for total COD removal. • Fenton oxidation was highly-efficient method for inert COD removal. • BOD5/COD ratio of leachate concentrate raised from 0.04 to 0.4. The primary aim of this study is inert COD removal from leachate nanofiltration concentrate because of its high concentration of resistant organic pollutants. Within this framework, this study focuses on the treatability of leachate nanofiltration concentrate through Fenton oxidation and optimization of process parameters to reach the maximum pollutant removal by using response surface methodology (RSM). Initial pH, Fe2+ concentration, H2O2/Fe2+ molar ratio and oxidation time are selected as the independent variables, whereas total COD, color, inert COD and UV254 removal are selected as the responses. According to the ANOVA results, the R2 values of all responses are found to be over 95%. Under the optimum conditions determined by the model (pH: 3.99, Fe2+: 150 mmol/L, H2O2/Fe2+: 3.27 and oxidation time: 84.8 min), the maximum COD removal efficiency is determined as 91.4% by the model. The color, inert COD and UV254 removal efficiencies are determined to be 99.9%, 97.2% and 99.5%, respectively, by the model, whereas the total COD, color, inert COD and UV254 removal efficiencies are found respectively to be 90%, 96.5%, 95.3% and 97.2%, experimentally under the optimum operating conditions. The Fenton process improves the biodegradability of the leachate NF concentrate, increasing the BOD5/COD ratio from the value of 0.04 to the value of 0.4. The operational cost of the process is calculated to be 0.238 €/g CODremoved. The results indicate that the Fenton oxidation process is an efficient and economical technology in improvement of the biological degradability of leachate nanofiltration concentrate and in removal of resistant organic pollutants.

关键词： Concentrated leachate Fenton oxidation Central composite design Biodegradability Inert COD

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Review on mechanism and process of surface polishing using lasers

Arun KRISHNAN, Fengzhou FANG

《机械工程前沿（英文）》 2019年第14卷第3期页码 299-319 doi: 10.1007/s11465-019-0535-0

摘要： Laser polishing is a technology of smoothening the surface of various materials with highly intense laser beams. When these beams impact on the material surface to be polished, the surface starts to be melted due to the high temperature. The melted material is then relocated from the ‘peaks to valleys’ under the multidirectional action of surface tension. By varying the process parameters such as beam intensity, energy density, spot diameter, and feed rate, different rates of surface roughness can be achieved. High precision polishing of surfaces can be done using laser process. Currently, laser polishing has extended its applications from photonics to molds as well as bio-medical sectors. Conventional polishing techniques have many drawbacks such as less capability of polishing freeform surfaces, environmental pollution, long processing time, and health hazards for the operators. Laser polishing on the other hand eliminates all the mentioned drawbacks and comes as a promising technology that can be relied for smoothening of initial topography of the surfaces irrespective of the complexity of the surface. Majority of the researchers performed laser polishing on materials such as steel, titanium, and its alloys because of its low cost and reliability. This article gives a detailed overview of the laser polishing mechanism by explaining various process parameters briefly to get a better understanding about the entire polishing process. The advantages and applications are also explained clearly to have a good knowledge about the importance of laser polishing in the future.

关键词： laser polishing surface roughness process parameters mechanism

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Tool path strategy and cutting process monitoring in intelligent machining

Ming CHEN, Chengdong WANG, Qinglong AN, Weiwei MING

《机械工程前沿（英文）》 2018年第13卷第2期页码 232-242 doi: 10.1007/s11465-018-0469-y

摘要：

Intelligent machining is a current focus in advanced manufacturing technology, and is characterized by high accuracy and efficiency. A central technology of intelligent machining—the cutting process online monitoring and optimization—is urgently needed for mass production. In this research, the cutting process online monitoring and optimization in jet engine impeller machining, cranio-maxillofacial surgery, and hydraulic servo valve deburring are introduced as examples of intelligent machining. Results show that intelligent tool path optimization and cutting process online monitoring are efficient techniques for improving the efficiency, quality, and reliability of machining.

关键词： intelligent machining tool path strategy process optimization online monitoring

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Seasonal and treatment-process variations in invertebrates in drinking water treatment plants

Zhiling Wu, Xianchun Tang, Hongbin Chen

《环境科学与工程前沿（英文）》 2021年第15卷第4期 doi: 10.1007/s11783-020-1354-6

摘要： Abstract • Seasonal and treatment-process variations in invertebrates in a DWTP were analyzed. • The propagation and leakage of invertebrates in BAC filter were the most serious. • Invertebrates can survive and reproduce in chlorine disinfected clear water tanks. • Proportions of endogenous invertebrates increased along the treatment process. Problems associated with excessive propagation and leakage of invertebrates in drinking water have received increasing attention in recent years. We performed a monthly survey of invertebrate abundance and taxa in the effluent of each treatment stage in a drinking water treatment plant between May 2015 and April 2016 and analyzed seasonal and treatment-process variations in invertebrates. The results showed that invertebrate abundances in raw water, effluent of the biological activated carbon (BAC) filter, and finished water significantly correlated with water temperature, whereas no correlation was observed between water temperature and invertebrate abundance in the effluents of the sedimentation tank and sand filter. The dominant taxa in the effluent of each treatment stage were rotifers, nematodes, and crustaceans. The sedimentation tank could efficiently remove invertebrates with an annual average removal rate of 92%. The propagation and leakage of invertebrates occurred in the sand and BAC filters but more seriously in the latter. The average reproduction rate in the BAC filter was 268.8% with rotifers as the taxon that leaked the most. Invertebrate survival and reproduction were also observed in the chlorine-disinfected clean water reservoir with an average reproduction rate of 41.9%. Owing to differences in chlorine resistance, the reproduction ability of the dominant taxa was in the order nematodes>crustaceans>rotifers. The proportion of endogenous invertebrates gradually increased along the treatment process. The average proportion of endogenous invertebrates in the finished water was higher than 79.0%. Our findings suggested that waterworks should pay more attention to endogenous invertebrate growth.

关键词： Invertebrates Drinking water Seasonal variations Treatment process

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Special issue on “Green chemical process and intensification”

《化学科学与工程前沿（英文）》 2022年第16卷第11期页码 1533-1535 doi: 10.1007/s11705-022-2263-y

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Sulfate digestion process for high purity TiO

T. A. LASHEEN

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 155-160 doi: 10.1007/s11705-009-0005-z

摘要： A titania slag product of Rosetta ilmenite assaying 72% TiO is treated by the sulfate process option of the pigmentary TiO manufacture. The relevant factors of acid concentration, particle size, slag/acid ratio besides the reaction temperature, and time have been studied. After dissolving the cured mass in dilute acid and clarification, the obtained solution was subjected to hydrolysis of its titanium content. The final product was bleached under reducing conditions to redissolve the residual coloring impurities before being dewatered and calcinated. The obtained results indicated that a leaching efficiency of about 92% was realized due to the presence of some refractory components in the working slag material, namely, rutile and magnesium iron titanate. The obtained white pigment assay attained up to 99.85% TiO , while the analyzed impurities involve 77 ppm Mn and only 14 and 7 ppm of total iron and V, respectively.

关键词： titania slag sulfate process pigment

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Multiscale process systems engineering—analysis and design of chemical and energy systems from moleculardesign up to process optimization

《化学科学与工程前沿（英文）》 2022年第16卷第2期页码 137-140 doi: 10.1007/s11705-021-2135-x

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A stepwise process for carbon dioxide sequestration using magnesium silicates

Johan FAGERLUND, Experience NDUAGU, Ron ZEVENHOVEN, Inês ROMÃO,

《化学科学与工程前沿（英文）》 2010年第4卷第2期页码 133-141 doi: 10.1007/s11705-009-0259-5

摘要： This work involves the production of magnesium in the form of Mg(OH) from serpentinite rock (nickel mine tailing) material followed by conversion into MgCO using a pressurised fluidised bed (PFB) reactor operating at 400°C–600°C and pressures up to 2.85MPa. Our approach is rooted in the thermodynamic fact that the reaction between Mg(OH) and gaseous CO forming MgCO and water releases significant amounts of heat. The main problem is, however, the chemical kinetics; the reaction is slow and has to be accelerated in order to be used in an economically viable process for large-scale (~1Mt/a) CO sequestration. We have constructed a lab-scale PFB reactor test-setup for optimising the carbonation reaction. At high enough temperatures and conversion levels the reaction should provide the heat for the proceeding Mg(OH) production step, making the overall process energy neutral. So far we have been able to achieve a conversion degree of 26% at 500°C and 2.85MPa after 30min (particle size 125–212μm). In this paper the test facility and our latest results and progress on CO mineral carbonation are summarised. Also, the possible integration of the iron as a feedstock for iron and steel production will be briefly addressed. An interesting side-effect of this carbon dioxide capture and storage (CCS) route is that significant amounts of iron are obtained from the serpentinite rock material. This is released during the Mg(OH) production and can be of great interest to the iron- and steel producing sector, which at the same time is Finland’s largest CO producer.

关键词： carbonation reaction reactor producer large-scale process