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High-gravity intensified iron-carbon micro-electrolysis for degradation of dinitrotoluene

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1595-1605 doi: 10.1007/s11705-022-2204-9

摘要： The application of iron–carbon (Fe–C) micro-electrolysis to wastewater treatment is limited by the passivation potential of the Fe–C packing. In order to address this problem, high-gravity intensified Fe–C micro-electrolysis was proposed in this study for degradation of dinitrotoluene wastewater in a rotating packed bed (RPB) using commercial Fe–C particles as the packing. The effects of reaction time, high-gravity factor, liquid flow rate and initial solution pH were investigated. The degradation intermediates were determined by gas chromatography-mass spectrometry, and the possible degradation pathways of nitro compounds by Fe–C micro-electrolysis in RPB were also proposed. It is found that under optimal conditions, the removal rate of nitro compounds reaches 68.4% at 100 min. The removal rate is maintained at approximately 68% after 4 cycles in RPB, but it is decreased substantially from 57.9% to 36.8% in a stirred tank reactor. This is because RPB can increase the specific surface area and the renewal of the liquid–solid interface, and as a result the degradation efficiency of Fe–C micro-electrolysis is improved and the active sites on the Fe–C surface can be regenerated for continuous use. In conclusion, high-gravity intensified Fe–C micro-electrolysis can weaken the passivation of Fe–C particles and extend their service life.

关键词： high-gravity technology     rotating packed bed     Fe–C micro-electrolysis     dinitrotoluene wastewater     active sites    

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microbial fuel cell for enhancing the nitrogen removal of the anammox process coupled with iron-carbon micro-electrolysis

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1409-3

摘要：

• MFC promoted the nitrogen removal of anammox with Fe-C micro-electrolysis.

关键词： Waste tire     MFCs     Micro-electrolysis     Anammox     Feammox    

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Application of Fe

Xiaowei ZHANG,Qinyan YUE,Dongting YUE,Baoyu GAO,Xiaojuan WANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第3期   页码 402-410 doi: 10.1007/s11783-014-0659-8

摘要： Dyes are common pollutants in textile wastewaters, and the treatment of the wastewater has now attracted much attention due to its wide application and low biodegradability. In this study, Fe /C/Clay ceramics, a kind of novel micro-electrolysis filler, were sintered and employed in a dynamic micro-electrolysis reactor for synthetic Acid Red 73 (AR73) and Reactive Blue 4 (RB4) wastewater treatment. The effects of influent pH, hydraulic retention time (HRT), and aeration on the decoloration efficiencies of AR73 and RB4 were studied. The optimum conditions for wastewater treatment were: AR73, influent pH of 4, HRT of 2 h and aeration; RB4, influent pH of 5, HRT of 6 h and aeration. Under the optimum conditions, decoloration efficiency of AR73 and RB4 wastewater was 96% and 83%, respectively. Results of UV-vis spectrum scanning demonstrated that the chromophores were broken. Continuous running tests showed that improvement of micro-electrolysis system with Fe /C/Clay ceramics for AR73 and RB4 synthetic wastewater treatment could avoid failure of micro-electrolysis reactor, which indicated great potential for the practical application of the ceramics in the field of actual industrial wastewater treatment.

关键词： Fe0/C/Clay ceramics     micro-electrolysis     Acid Red 73     Reactive Blue 4     synthetic wastewater    

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The world’s first offshore wind power non-desalination of seawater electrolysis for hydrogen production

《能源前沿（英文）》 2023年 第17卷 第3期   页码 317-319 doi: 10.1007/s11708-023-0888-2

摘要： The world’s first offshore wind power non-desalination of seawater electrolysis for hydrogen production successfully tested in Fujian, China

关键词： China     wind power non    

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Microbial electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced

Jingya SHEN,Yuliang SUN,Liping HUANG,Jinhui YANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 1084-1095 doi: 10.1007/s11783-015-0805-y

摘要： Cobalt and copper recovery from aqueous Co(II) and Cu(II) is one critical step for cobalt and copper wastewaters treatment. Previous tests have primarily examined Cu(II) and Co(II) removal in microbial electrolysis cells (MECs) with abiotic cathodes and driven by microbial fuel cell (MFCs). However, Cu(II) and Co(II) removal rates were still slow. Here we report MECs with biocathodes and driven by MFCs where enhanced removal rates of 6.0±0.2 mg?L ?h for Cu(II) at an initial concentration of 50 mg?L and 5.3±0.4 mg?L h for Co(II) at an initial 40 mg?L were achieved, 1.7 times and 3.3 times as high as those in MECs with abiotic cathodes and driven by MFCs. Species of Cu(II) was reduced to pure copper on the cathodes of MFCs whereas Co(II) was removed associated with microorganisms on the cathodes of the connected MECs. Higher Cu(II) concentrations and smaller working volumes in the cathode chambers of MFCs further improved removal rates of Cu(II) (115.7 mg?L ?h ) and Co(II) (6.4 mg?L ?h ) with concomitantly achieving hydrogen generation (0.05±0.00 mol?mol COD). Phylogenetic analysis on the biocathodes indicates dominantly accounted for 67.9% of the total reads, followed by (14.0%), (6.1%), (2.5%), (1.4%), and (1.0%). This study provides a beneficial attempt to achieve simultaneous enhanced Cu(II) and Co(II) removal, and efficient Cu(II) and Co(II) wastewaters treatment without any external energy consumption.

关键词： biocathode     microbial electrolysis cell     microbial fuel cell     Cu(II) removal     Co(II) removal    

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High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

《能源前沿（英文）》 doi: 10.1007/s11708-023-0892-6

摘要： High entropy materials (HEMs) have developed rapidly in the field of electrocatalytic water-electrolysis for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) due to their unique properties. In particular, HEM catalysts are composed of many elements. Therefore, they have rich active sites and enhanced entropy stability relative to single atoms. In this paper, the preparation strategies and applications of HEM catalysts in electrochemical water-electrolysis are reviewed to explore the stabilization of HEMs and their catalytic mechanisms as well as their application in support green hydrogen production. First, the concept and four characteristics of HEMs are introduced based on entropy and composition. Then, synthetic strategies of HEM catalysts are systematically reviewed in terms of the categories of bottom-up and top-down. The application of HEMs as catalysts for electrochemical water-electrolysis in recent years is emphatically discussed, and the mechanisms of improving the performance of electrocatalysis is expounded by combining theoretical calculation technology and ex-situ/in situ characterization experiments. Finally, the application prospect of HEMs is proposed to conquer the challenges in HEM catalyst fabrications and applications.

关键词： high-entropy     electrocatalysis     synthetic methods     water-electrolysis     hydrogen and oxygen evolutions    

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Flexible micro flow sensor for micro aerial vehicles

Rong ZHU, Ruiyi QUE, Peng LIU

《机械工程前沿（英文）》 2017年 第12卷 第4期   页码 539-545 doi: 10.1007/s11465-017-0427-0

摘要：

This article summarizes our studies on micro flow sensors fabricated on a flexible polyimide circuit board by a low-cost hybrid process of thin-film deposition and circuit printing. The micro flow sensor has merits of flexibility, structural simplicity, easy integrability with circuits, and good sensing performance. The sensor, which adheres to an object surface, can detect the surface flow around the object. In our study, we install the fabricated micro flow sensors on micro aerial vehicles (MAVs) to detect the surface flow variation around the aircraft wing and deduce the aerodynamic parameters of the MAVs in flight. Wind tunnel experiments using the sensors integrated with the MAVs are also conducted.

关键词： micro flow sensor     flexible sensor     surface flow sensing     aerodynamic parameter     micro aerial vehicle (MAV)    

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矿浆电解过程的浸出机理

杨显万,张英杰,邓纶浩,邱定蕃

《中国工程科学》 2000年 第2卷 第6期   页码 49-51

摘要：

介绍了高铅铜型难处理金矿矿浆电解浸出机理的研究结果。金精矿在矿浆电解时，铅的浸出可通过化学溶解、化学氧化、阳极氧化三种途径；铅浸出的主要途径是靠化学溶解，矿粒与阳极接触而被氧化对浸出的贡献不大。

关键词： 矿浆电解     浸出     机理    

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Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

《能源前沿（英文）》 doi: 10.1007/s11708-023-0901-9

摘要： Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance degradation of SOCs. Coating on the interconnector surface is an important approach to inhibit the oxidation and Cr migration of the interconnector. Herein, (La0.75Sr0.25)0.95MnO3–δ (LSM) and Mn1.5Co1.5O4 (MCO) are used to fabricate the coatings of interconnector. Two advanced thermal spray technology, atmospheric plasma spraying (APS) and low-pressure plasma spray (LPPS), are adopted for the coating preparation. The electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition performance of the coatings are tested and evaluated. The result indicates that MCO can generate more uniform and denser coatings than LSM. In addition, MCO coatings prepared by LPPS shows the best electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition. The initial area specific resistance (ASR) is 0.0027 Ω·cm2 at 800 °C. After 4 cooling cycle tests, the ASR increases to 0.0032 Ω·cm2 but lower than other samples. Meanwhile, the relative intense of Cr at the interface of SUS430 with MCO coatings fabricated by LPPS is lower than that of MCO fabricated by APS after 4 rising and cooling cycle operations, showing more favorable Cr diffusion inhibition performance.

关键词： interconnector coating     plasma spray     electrochemical performance     Cr diffusion inhibition     solid oxide cells (SOCs)    

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A knowledge reasoning Fuzzy-Bayesian network for root cause analysis of abnormal aluminum electrolysis

Weichao Yue, Xiaofang Chen, Weihua Gui, Yongfang Xie, Hongliang Zhang

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 414-428 doi: 10.1007/s11705-017-1663-x

摘要： Root cause analysis (RCA) of abnormal aluminum electrolysis cell condition has long been a challenging industrial issue due to its inherent complexity in analyzing based on multi-source knowledge. In addition, accurate RCA of abnormal aluminum electrolysis cell condition is the precondition of improving current efficiency. RCA of abnormal condition is a complex work of multi-source knowledge fusion, which is difficult to ensure the RCA accuracy of abnormal cell condition because of dwindling and frequent flow of experienced technicians. In view of this, a method based on Fuzzy-Bayesian network to construct multi-source knowledge solidification reasoning model is proposed. The method can effectively fuse and solidify the knowledge, which is used to analyze the cause of abnormal condition by technicians providing a clear and intuitive framework to this complex task, and also achieve the result of root cause automatically. The proposed method was verified under 20 sets of abnormal cell conditions, and implements root cause analysis by finding the abnormal state of root node, which has a maximum posterior probability by Bayesian diagnosis reasoning. The accuracy of the test results is up to 95%, which shows that the knowledge reasoning feasibility for RCA of aluminum electrolysis cell.

关键词： abnormal aluminum electrolysis cell condition     Fuzzy-Bayesian network     multi-source knowledge solidification and reasoning     root cause analysis    

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Effects of operational and structural parameters on cell voltage of industrial magnesium electrolysis

Ze Sun,Chenglin Liu,Guimin Lu,Xingfu Song,Jianguo Yu

《化学科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 522-531 doi: 10.1007/s11705-015-1539-x

摘要： Electric field is the energy foundation of the electrolysis process and the source of the multiphysical fields in a magnesium electrolysis cell. In this study, a three-dimensional numerical model was developed and used to calculate electric field at the steady state through the finite element analysis. Based on the simulation of the electric field, the operational and structural parameters, such as the current intensity, anode thickness, cathode thickness, and anode-cathode distance (ACD), were investigated to obtain the minimum cell voltage. The optimization is to obtain the minimum resistance voltage which has a significant effect on the energy consumption in the magnesium electrolysis process. The results indicate that the effect of the current intensity on the voltage could be ignored and the effect of the ACD is obvious. Moreover, there is a linear decrease between the voltage and the thicknesses of the anode and cathode; and the anode-cathode working height also has a significant effect on the voltage.

关键词： finite element method     magnesium electrolysis cell     electric field    

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Power-to-chemicals: sustainable liquefaction of food waste with plasma-electrolysis

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 594-605 doi: 10.1007/s11705-022-2255-y

摘要： The increasing amount of food waste from various industrial, agricultural, and household sources is an environmental burden if managed inappropriately. Numerous waste management approaches have been developed for the disposal of food waste, but still suffer from either high cost, production of toxic by-products, or secondary environmental pollutions. Herein, we report a new and sustainable plasma electrolysis biorefinery route for the rapid and efficient liquefaction of food waste. During the plasma electrolysis process, only the solvent is added to liquefy the waste, and anions in the waste can contribute to catalyzing the biowaste conversion. While liquefying the waste, the highly reactive species produced in the plasma electrolysis process can efficiently reduce the content of O, N, and Cl in the liquefied products and oxidize most of the metals into solid residues. Especially, the removal rate of Na and K elements was greater than 81%, which is significantly higher than using the traditional oil bath liquefaction, resulting in a relatively high-quality biocrude oil with a high heating value of 25.86 MJ·kg–1. Overall, this proposed strategy may provide a new sustainable and eco-friendly avenue for the power-to-chemicals valorization of food waste under benign conditions.

关键词： plasma electrolysis     food waste     liquefaction     resource recovery    

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固体氧化物电解池共电解H2O/CO2研究进展

范慧,宋世栋,韩敏芳

《中国工程科学》 2013年 第15卷 第2期   页码 107-112

摘要：

固体氧化物电解池（SOEC）作为一种新的能源利用方式，可以将电能转化为化学能，具有高效、洁净、环保等优点。本文介绍了固体氧化物电解池的结构特点及其用于H2O/CO2的共电解制备H2和CO的工作原理，综述了固体氧化物电解池的组成形式，以及单片电解池和电解池堆用于H2O/CO2共电解反应的国内外研究进展，并阐述了提高固体氧化物电解池共电解效率所亟需解决的问题。

关键词： 固体氧化物电解池     H2O/CO2共电解     合成气     电解效率     水电解    

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Pesticide wastewater treatment using the combination of the microbial electrolysis desalination and chemical-production

Songwei Lin, Yaobin Lu, Bo Ye, Cuiping Zeng, Guangli Liu, Jieling Li, Haiping Luo, Renduo Zhang

《环境科学与工程前沿（英文）》 2020年 第14卷 第1期 doi: 10.1007/s11783-019-1191-7

摘要： MEDCC combined with Fenton process was developed to treat real pesticide wastewater. Pesticide removal was attributable to desalination in the MEDCC. High COD removal was attributable to organic distributions in different chambers. The combination of the microbial electrolysis desalination and chemical-production cell (MEDCC) and Fenton process for the pesticide wastewater treatment was investigate in this study. Real wastewater with several toxic pesticides, 1633 mg/L COD, and 200 in chromaticity was used for the investigation. Results showed that desalination in the desalination chamber of MEDCC reached 78%. Organics with low molecular weights in the desalination chamber could be removed from the desalination chamber, resulting in 28% and 23% of the total COD in the acid-production and cathode chambers, respectively. The desalination in the desalination chamber and organic transfer contributed to removal of pesticides (e.g., triadimefon), which could not be removed with other methods, and of the organics with low molecular weights. The COD in the effluent of the MEDCC combined the Fenton process was much lower than that in the perixo-coagulaiton process (<150 vs. 555 mg/L). The combined method consumed much less energy and acid for the pH adjustment than that the Fenton.

关键词： Pesticide wastewater     COD removal     Microbial electrolysis desalination and chemical-production cell     Energy consumption     Fenton oxidation    

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Effects of bicarbonate and cathode potential on hydrogen production in a biocathode electrolysis cell

Dawei LIANG,Yanyan LIU,Sikan PENG,Fei LAN,Shanfu LU,Yan XIANG

《环境科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 624-630 doi: 10.1007/s11783-013-0584-2

摘要： A biocathode with microbial catalyst in place of a noble metal was successfully developed for hydrogen evolution in a microbial electrolysis cell (MEC). The strategy for fast biocathode cultivation was demonstrated. An exoelectrogenic reaction was initially extended with an H -full atmosphere to enrich H -utilizing bacteria in a MEC bioanode. This bioanode was then inversely polarized with an applied voltage in a half-cell to enrich the hydrogen-evolving biocathode. The electrocatalytic hydrogen evolution reaction (HER) kinetics of the biocathode MEC could be enhanced by increasing the bicarbonate buffer concentration from 0.05 mol·L to 0.5 mol·L and/or by decreasing the cathode potential from -0.9 V to -1.3 V vs. a saturated calomel electrode (SCE). Within the tested potential region in this study, the HER rate of the biocathode MEC was primarily influenced by the microbial catalytic capability. In addition, increasing bicarbonate concentration enhances the electric migration rate of proton carriers. As a consequence, more mass H can be released to accelerate the biocathode-catalyzed HER rate. A hydrogen production rate of 8.44 m ·m ·d with a current density of 951.6 A·m was obtained using the biocathode MEC under a cathode potential of -1.3 V vs. SCE and 0.4 mol·L bicarbonate. This study provided information on the optimization of hydrogen production in biocathode MEC and expanded the practical applications thereof.

关键词： microbial electrolysis cell (MEC)     biocathode     hydrogen production     bicarbonate     cathode potential    

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标题 作者 时间 类型 操作

High-gravity intensified iron-carbon micro-electrolysis for degradation of dinitrotoluene

期刊论文

microbial fuel cell for enhancing the nitrogen removal of the anammox process coupled with iron-carbon micro-electrolysis

期刊论文

Application of Fe

Xiaowei ZHANG,Qinyan YUE,Dongting YUE,Baoyu GAO,Xiaojuan WANG

期刊论文

The world’s first offshore wind power non-desalination of seawater electrolysis for hydrogen production

期刊论文

Microbial electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced

Jingya SHEN,Yuliang SUN,Liping HUANG,Jinhui YANG

期刊论文

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

期刊论文

Flexible micro flow sensor for micro aerial vehicles

Rong ZHU, Ruiyi QUE, Peng LIU

期刊论文

矿浆电解过程的浸出机理

杨显万,张英杰,邓纶浩,邱定蕃

期刊论文

Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

期刊论文

A knowledge reasoning Fuzzy-Bayesian network for root cause analysis of abnormal aluminum electrolysis

Weichao Yue, Xiaofang Chen, Weihua Gui, Yongfang Xie, Hongliang Zhang

期刊论文

Effects of operational and structural parameters on cell voltage of industrial magnesium electrolysis

Ze Sun,Chenglin Liu,Guimin Lu,Xingfu Song,Jianguo Yu

期刊论文

Power-to-chemicals: sustainable liquefaction of food waste with plasma-electrolysis

期刊论文

固体氧化物电解池共电解H2O/CO2研究进展

范慧,宋世栋,韩敏芳

期刊论文

Pesticide wastewater treatment using the combination of the microbial electrolysis desalination and chemical-production

Songwei Lin, Yaobin Lu, Bo Ye, Cuiping Zeng, Guangli Liu, Jieling Li, Haiping Luo, Renduo Zhang

期刊论文

Effects of bicarbonate and cathode potential on hydrogen production in a biocathode electrolysis cell

Dawei LIANG,Yanyan LIU,Sikan PENG,Fei LAN,Shanfu LU,Yan XIANG

期刊论文