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CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction

《环境科学与工程前沿（英文）》 2022年 第16卷 第5期 doi: 10.1007/s11783-022-1539-2

摘要：

• CeO2 doping significantly improved low-temperature NH3-SCR activity on FeTiOx.

关键词： NH3-SCR     CeO2 doping     Low-temperature NOx removal     Improved redox property     In situ XAFS analysis    

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Remediation of soil heavily polluted with polychlorinated biphenyls using a low-temperature plasma technique

Xiuhua LI, Haibo ZHANG, Yongming LUO, Ying TENG

《环境科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 277-283 doi: 10.1007/s11783-013-0562-8

摘要： Polychlorinated biphenyls PCBs) were removed by low-temperature plasma technique (dielectric barrier discharge) from heavily polluted soil and their intermediate products were analyzed. The removal rate ranged from 40.1 to 84.6% by different treatments, and they were also influenced significantly ( <0.01) by soil particle-size, electric power, gas flow rate and reaction time. The optimal reaction conditions of PCB removal from the soil were obtained experimentally when soil particle-size, electrical power, flow rate and reaction time were 5–10 mm, 21 w, 120 mL· min and 90 min, respectively. However, decreasing electrical power, flow rate and reaction time to 18 w, 60 mL· min and 60 min respectively were also acceptable in view of the cost of remediation. This technique was characterized by the additional advantage of thorough oxidation of PCBs in the soil, with no formation of intermediate products after reaction. The technique therefore shows some promise for application in the remediation of soils contaminated with persistent organic pollutants in brown field sites in urban areas.

关键词： polychlorinated biphenyls     low-temperature plasma     soil contamination     intermediate products    

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A review of low-temperature plasma-assisted machining: from mechanism to application

《机械工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0734-y

摘要： Materials with high hardness, strength or plasticity have been widely used in the fields of aviation, aerospace, and military, among others. However, the poor machinability of these materials leads to large cutting forces, high cutting temperatures, serious tool wear, and chip adhesion, which affect machining quality. Low-temperature plasma contains a variety of active particles and can effectively adjust material properties, including hardness, strength, ductility, and wettability, significantly improving material machinability. In this paper, we first discuss the mechanisms and applications of low-temperature plasma-assisted machining. After introducing the characteristics, classifications, and action mechanisms of the low-temperature plasma, we describe the effects of the low-temperature plasma on different machining processes of various difficult-to-cut materials. The low-temperature plasma can be classified as hot plasma and cold plasma according to the different equilibrium states. Hot plasma improves material machinability via the thermal softening effect induced by the high temperature, whereas the main mechanisms of the cold plasma can be summarized as chemical reactions to reduce material hardness, the hydrophilization effect to improve surface wettability, and the Rehbinder effect to promote fracture. In addition, hybrid machining methods combining the merits of the low-temperature plasma and other energy fields like ultrasonic vibration, liquid nitrogen, and minimum quantity lubrication are also described and analyzed. Finally, the promising development trends of low-temperature plasma-assisted machining are presented, which include more precise control of the heat-affected zone in hot plasma-assisted machining, cold plasma-assisted polishing of metal materials, and further investigations on the reaction mechanisms between the cold plasma and other materials.

关键词： low-temperature plasma     difficult-to-cut material     machinability     hydrophilization effect     Rehbinder effect    

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Development of highly active coated monolith SCR catalyst with strong abrasion resistance for low-temperature

Lina GAN,Shan LEI,Jian YU,Hongtao MA,Yo YAMAMOTO,Yoshizo SUZUKI,Guangwen XU,Zhanguo ZHANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 979-987 doi: 10.1007/s11783-015-0824-8

摘要： Monolith SCR catalysts coated with V O -WO /TiO were prepared by varying binder and coating thickness. Comparing with a monolith extruded with 100% V O -WO /TiO powder, a coated monolith with a catalyst-coating layer of 260 μm in thickness exhibited the similar initial NO reduction activity at 250°C. After 4 h abrasion (attrition) in an air stream containing 300 g·m fine sands (50–100 μm) at a superficial gas velocity of 10 m·s , the catalyst still has the activity as a 100% molded monolith does in a 24-h activity test and it retains about 92% of its initial activity at 250°C. Estimation of the equivalent durable hours at a fly ash concentration of 1.0 g·m in flue gas and a gas velocity of 5 m·s demonstrated that this coated monolith catalyst is capable of resisting abrasion for 13 months without losing more than 8% of its initial activity. The result suggests the great potential of the coated monolith for application to de-NO of flue gases with low fly ash concentrations from, such as glass and ceramics manufacturing processes.

关键词： coated monolith     low-temperature denitration     abrasion resistance     attrition    

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Excellent performance of Cu-Mn/Ti-sepiolite catalysts for low-temperature CO oxidation

Yong Song,Lisha Liu,Zhidan Fu,Qing Ye,Shuiyuan Cheng,Tianfang Kang,Hongxing Dai

《环境科学与工程前沿（英文）》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0908-8

摘要： Sepiolite is clay mineral with a 2:1 layered structure. Ti-pillars have an impact on physicochemical property of the sample. 30Mn5Cu/Ti-Sep shows excellent catalytic activity for the oxidation of CO. The interaction, reducibility, and oxygen mobility govern the activity. The Ti-modified sepiolite (Ti-Sep)-supported Mn-Cu mixed oxide ( Mn5Cu/Ti-Sep) catalysts were synthesized using the co-precipitation method. The materials were characterized by the X-ray diffraction scanning electron microscope, N adsorption-desorption, H -TPR, O -TPD, and XPS techniques, and their catalytic activities for CO oxidation were evaluated. It was found that the catalytic activities of Mn5Cu/Ti-Sep were higher than those of 5Cu/Ti-Sep and 30Mn/Ti-Sep, and the Mn/Cu molar ratio had a distinct influence on catalytic activity of the sample. Among the Mn5Cu/Ti-Sep samples, the 30Mn5Cu/Ti-Sep catalyst showed the best activity (which also outperformed the 30Mn5Cu/Sep catalyst), giving the highest reaction rate of 0.875 × 10 mmol·g ·s and the lowest and of 56°C and 86°C, respectively. Moreover, the 30Mn5Cu/Ti-Sep possessed the best low-temperature reducibility, the lowest O desorption temperature, and the highest surface Mn /Mn atomic ratio. It is concluded that factors, such as the strong interaction between the copper or manganese oxides and the Ti-Sep support, good low-temperature reducibility, and good mobility of chemisorbed oxygen species, were responsible for the excellent catalytic activity of 30Mn5Cu/Ti-Sep.

关键词： Ti-modified sepiolite     Supported Mn-Cu mixed oxide     Low-temperature reducibility     Strong metal-support interaction     CO oxidation    

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NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1696-y

摘要：

● Microwave-assisted catalytic NH3-SCR reaction over spinel oxides is carried out.

关键词： Microwave field     Spinel oxides     NOx     Selective catalytic reduction    

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Promotional effect of ion-exchanged K on the low-temperature hydrothermal stability of Cu/SAPO-34 and

Chen Wang, Jun Wang, Jianqiang Wang, Meiqing Shen

《环境科学与工程前沿（英文）》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1322-1

摘要： Abstract • K+ hinder the structural degradation of Cu/SAPO-34 under humid condition<100°C. • K+ on Cu/SAPO-34 brings lower acidity and inferior SCR activity at high temperature. • Fe/Beta was used to compensate the low activity of Cu/SAPO-34 at high temperature. • The hybrid catalysts with KCu/SAPO-34 and Fe/Beta show a great potential for using. K ions were introduced onto Cu/SAPO-34 catalysts via the ion-exchange process in order to improve their stability under low-temperature hydrothermal aging. The changes in structure and copper-species contents of these catalysts upon hydrothermal aging were probed in order to investigate their effects on selective catalytic reduction (SCR) activity. For the fresh Cu/SAPO-34 catalysts, K ions had little influence on the chabazite framework but effected their acidities by exchanging with acid sites. After hydrothermal aging, the structural integrity and amount of active sites decreased on pure Cu/SAPO-34. While the K-loaded catalysts showed improved chabazite structure, acidity, and active site conservation with increasing K loading. However, although the 0.7 wt% K catalyst maintained the same crystallinity, active site abundance, and low-temperature SCR activity as the fresh catalyst upon aging, an apparent decrease in SCR activity at high temperature was observed because of the inevitable decrease in the number of Brönsted acid sites. To compensate for the activity disadvantage of K-loaded Cu/SAPO-34 at high temperature, Fe/Beta catalysts were co-employed with K-loaded Cu/SAPO-34, and a wide active temperature window of SCR activity was obtained. Thus, our study reveals that a combined system comprising Fe/Beta and K-loaded Cu/SAPO-34 catalysts shows promise for the elimination of NOx in real-world applications.

关键词： Selective catalytic reduction     Cu/SAPO-34 catalyst     Ion-exchanged K     Low-temperature hydrothermal stability     Fe/Beta catalyst    

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Low-temperature caproate production, microbial diversity, and metabolic pathway in xylose anaerobic fermentation

《环境科学与工程前沿（英文）》 2023年 第17卷 第3期 doi: 10.1007/s11783-023-1637-9

摘要：

● Converting xylose to caproate under a low temperature of 20 °C by MCF was verified.

关键词： Xylose fermentation     Caproate     Low temperature     Bifidobacterium     FAB pathway     RBO pathway    

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Study of the robustness of a low-temperature dual-pressure process for removal of CO

Stefania Moioli, Laura A. Pellegrini, Paolo Vergani, Fabio Brignoli

《化学科学与工程前沿（英文）》 2018年 第12卷 第2期   页码 209-225 doi: 10.1007/s11705-017-1688-1

摘要： The growing use of energy by most of world population and the consequent increasing demand for energy are making unexploited low quality gas reserves interesting from an industrial point of view. To meet the required specifications for a natural gas grid, some compounds need to be removed from the sour stream. Because of the high content of undesired compounds (i.e., CO ) in the stream to be treated, traditional purification processes may be too energy intensive and the overall system may result unprofitable, therefore new technologies are under study. In this work, a new process for the purification of natural gas based on a low temperature distillation has been studied, focusing on the dynamics of the system. The robustness of the process has been studied by dynamic simulation of an industrial-scale plant, with particular regard to the performances when operating conditions are changed. The results show that the process can obtain the methane product with a high purity and avoid the solidification of carbon dioxide.

关键词： CO2 capture     innovative process     cryogenic distillation     dynamic simulation     solid-liquid-vapor equilibrium    

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A two-stage deep freezing chemisorption cycle driven by low-temperature heat source

Yuanyang HU, Liwei WANG, Lu XU, Ruzhu WANG, Jeremiah KIPLAGAT, Jian WANG

《能源前沿（英文）》 2011年 第5卷 第3期   页码 263-269 doi: 10.1007/s11708-011-0152-z

摘要： A two-stage chemisorption cycle suitable for deep-freezing application driven by low- temperature heat source was proposed. Through two-stage desorption processes, the two-stage cycle can break through the limitations of the heating temperature and ambient cooling temperature. The two-stage cycle based on CaCl /BaCl -NH working pair can utilize the heat source with a temperature of above 75°C, and simultaneously realize deep-freezing all the year round. Experimental results and performance prediction show that the adsorption quantity of calcium, theoretical coefficient of performance (COP) and optimized specific cooling power (SCP) of the CaCl /BaCl -NH chemisorption system are 0.489 kg/kg (salt), 0.24 and 120.7 W/kg, when the heating temperature, ambient cooling temperature, pseudo-evaporating temperature and mass ratio of reacting salt and expanded graphite are 85, 30, -20, and 4∶1, respectively.

关键词： adsorption     freezing     desorption     heat source    

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Achieving High Strength and Tensile Ductility in Pure Nickel by Cryorolling with Subsequent Low-Temperature

Zhide Li,Hao Gu,Kaiguang Luo,Charlie Kong,Hailiang Yu,

《工程（英文）》 doi: 10.1016/j.eng.2023.01.019

摘要： ty. In this study, cryorolling under different strains followed by low-temperature short-time annealing was used to fabricate pure nickel sheets combining high strength with good ductility. The results show that, for different cryorolling strains, the uniform elongation was greatly increased without sacrificing the strength after annealing. A yield strength of 607 MPa and a uniform elongation of 11.7% were obtained after annealing at a small cryorolling strain (ε = 0.22), while annealing at a large cryorolling strain (ε = 1.6) resulted in a yield strength of 990 MPa and a uniform elongation of 6.4%. X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and electron backscattered diffraction (EBSD) were used to characterize the microstructure of the specimens and showed that the high strength could be attributed to strain hardening during cryorolling, with an additional contribution from grain refinement and the formation of dislocation walls. The high ductility could be attributed to annealing twins and micro-shear bands during stretching, which improved the strain hardening capacity. The results show that the synergistic effect of strength and ductility can be regulated through low-temperature short-time annealing with different cryorolling strains, which provides a new reference for the design of future thermo-mechanical processes.

关键词： Cryorolling     Annealing     Nickel     Strain hardening     Ductility    

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低温固体氧化物燃料电池的复合电解质材料

谢富丞,王诚,毛宗强

《中国工程科学》 2013年 第15卷 第2期   页码 72-76

摘要：

固体氧化物燃料电池（SOFC）是一种高效、环保的发电装置。低温化是SOFC的主要发展方向。探索适合在低温（400~600 ℃）条件下操作的高性能电解质材料是SOFC低温化发展的关键。近年来，研究人员发展了新型的复合电解质材料，取得了较好的成果。本文综述了近年来低温SOFC复合电解质材料的研究进展，简要介绍了复合电解质材料的特点、类型和传导机理。

关键词： 低温SOFC     复合电解质     传导机理    

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低温固体氧化物燃料电池电解质材料

韩 达,吴天植,辛显双,王绍荣,占忠亮

《中国工程科学》 2013年 第15卷 第2期   页码 66-71

摘要：

低温化是固体氧化物燃料电池（SOFC）发电技术的重要发展趋势。SOFC工作温度的降低不仅可极大地降低材料及制备成本，更重要的是可极大地提高其长期运行的稳定性。电解质是SOFC的核心部件，可以采用电解质薄膜化或新型电解质材料来降低SOFC的工作温度。本文概述了目前被广泛研究的低温SOFC的电解质材料，并从其结构及性能出发，重点阐述了它们各自的优点和局限性。

关键词： 低温SOFC     新型电解质     离子电导率    

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温差能与低温海水资源综合利用研究

付强,王国荣,周守为,钟林,张理,余兴勇,杨浦

《中国工程科学》 2021年 第23卷 第6期   页码 52-60 doi: 10.15302/J-SSCAE-2021.06.007

摘要：

我国海洋温差能资源量巨大，主要分布在广东省和南海海域，是区域能源结构优化以实现碳达峰、碳中和的有效支撑，也是未来我国南海、 21 世纪海上丝绸之路沿线诸多岛屿能源补给保障的重要途径；目前海洋温差能发电（ OTEC）技术和装备尚处于实验阶段，兆瓦级试验电站建设成本巨大，整体技术成熟度不及商业级利用规模，亟待发展突破。本文总结了国内外 OTEC 及综合利用的发展模式、技术装备所面临的挑战，针对南海温差能资源开发困境、广东省液化天然气（ LNG）冷能资源浪费等情况，提出了以 LNG 气化的低温海水替代深层海水进行温差能发电的新途径。建议以珠海 LNG 气化站为例，探索 LNG 冷能回收 – 温差能发电、低温冷海水综合利用示范基地的发展模式；通过初步概算示范基地的投资与收益，完成了相应模式的经济与技术可行性论证。相关发展模式建议、应用案例论证过程，可为我国温差能与低温海水资源综合利用提供技术借鉴和应用参考。

关键词： 海洋温差能     低温海水资源     LNG冷能     综合利用     温差能发电    

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Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 594-602 doi: 10.1007/s11705-017-1668-5

摘要： A mild deposition method was used to fabricate Mn-based catalysts on a UiO-66 carrier for the selective catalytic reduction of NO by NH (NH -SCR). The catalyst with 8.5 wt-% MnO loading had the highest catalytic activity for NH -SCR with a wide temperature window (100–290 °C) for 90% NO conversion. Characterization of the prepared MnO /UiO-66 catalysts showed that the catalysts had the crystal structure and porosity of the UiO-66 carrier and that the manganese particles were well-distributed on the surface of the catalyst. X-ray photoelectron spectroscopy analysis showed that there are strong interactions between the MnO and the Zr oxide secondary building units of the UiO-66 which has a positive effect on the catalytic activity. The 8.5 wt-% MnO catalyst maintained excellent activity during a 24-h stability test and exhibited good resistance to SO poisoning.

关键词： metal-organic framework     selective catalytic reduction     manganese oxides     deNOx     SO2 resistance    

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标题 作者 时间 类型 操作

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction

期刊论文

Remediation of soil heavily polluted with polychlorinated biphenyls using a low-temperature plasma technique

Xiuhua LI, Haibo ZHANG, Yongming LUO, Ying TENG

期刊论文

A review of low-temperature plasma-assisted machining: from mechanism to application

期刊论文

Development of highly active coated monolith SCR catalyst with strong abrasion resistance for low-temperature

Lina GAN,Shan LEI,Jian YU,Hongtao MA,Yo YAMAMOTO,Yoshizo SUZUKI,Guangwen XU,Zhanguo ZHANG

期刊论文

Excellent performance of Cu-Mn/Ti-sepiolite catalysts for low-temperature CO oxidation

Yong Song,Lisha Liu,Zhidan Fu,Qing Ye,Shuiyuan Cheng,Tianfang Kang,Hongxing Dai

期刊论文

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

期刊论文

Promotional effect of ion-exchanged K on the low-temperature hydrothermal stability of Cu/SAPO-34 and

Chen Wang, Jun Wang, Jianqiang Wang, Meiqing Shen

期刊论文

Low-temperature caproate production, microbial diversity, and metabolic pathway in xylose anaerobic fermentation

期刊论文

Study of the robustness of a low-temperature dual-pressure process for removal of CO

Stefania Moioli, Laura A. Pellegrini, Paolo Vergani, Fabio Brignoli

期刊论文

A two-stage deep freezing chemisorption cycle driven by low-temperature heat source

Yuanyang HU, Liwei WANG, Lu XU, Ruzhu WANG, Jeremiah KIPLAGAT, Jian WANG

期刊论文

Achieving High Strength and Tensile Ductility in Pure Nickel by Cryorolling with Subsequent Low-Temperature

Zhide Li,Hao Gu,Kaiguang Luo,Charlie Kong,Hailiang Yu,

期刊论文

低温固体氧化物燃料电池的复合电解质材料

谢富丞,王诚,毛宗强

期刊论文

低温固体氧化物燃料电池电解质材料

韩 达,吴天植,辛显双,王绍荣,占忠亮

期刊论文

温差能与低温海水资源综合利用研究

付强,王国荣,周守为,钟林,张理,余兴勇,杨浦

期刊论文

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

期刊论文