资源类型

期刊论文 18

年份

2023 3

2022 2

2021 1

2020 4

2018 2

2017 2

2015 1

2012 1

2011 1

2010 1

展开 ︾

关键词

乙烯 1

化学循环 1

石脑油裂解 1

过程强化 1

过程模拟 1

展开 ︾

检索范围：

排序： 展示方式：

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1937-1948 doi: 10.1007/s11705-023-2353-5

摘要： In this study, Bi2MoO6 with adjustable rich oxygen vacancies was prepared by a novel and simple solvothermal-photoreduction method which might be suitable for a large-scale production. The experiment results show that Bi2MoO6 with rich oxygen vacancies is an excellent photocatalyst. The photocatalytic ability of BMO-10 is 0.3 and 3.5 times higher than that of the pristine Bi2MoO6 for Rhodamine B degradation and Cr(VI) reduction, respectively. The results display that the band energy of the samples with oxygen vacancies was narrowed and the light absorption was broadened. Meanwhile, the efficiency of photogenerated electron-holes was increased and the separation and transfer speed of photogenerated carriers were improved. Therefore, this work provides a convenient and efficient method to prepare potential adjustable oxygen vacancy based photocatalysts to eliminate the pollution of dyes and Cr(VI) in water.

关键词： Bi2MoO6     oxygen vacancies     photoreduction     Cr(VI)     RhB    

HTML PDF 收藏

High butanol production by regulating carbon, redox and energy in Clostridia? ?

Jianfa Ou,Chao Ma,Ningning Xu,Yinming Du,Xiaoguang (Margaret) Liu

《化学科学与工程前沿（英文）》 2015年 第9卷 第3期   页码 317-323 doi: 10.1007/s11705-015-1522-6

摘要： Butanol is a promising biofuel with high energy intensity and can be used as gasoline substitute. It can be produced as a sustainable energy by microorganisms (such as Clostridia) from low-value biomass. However, the low productivity, yield and selectivity in butanol fermentation are still big challenges due to the lack of an efficient butanol-producing host strain. In this article, we systematically review the host cell engineering of Clostridia, focusing on (1) various strategies to rebalance metabolic flux to achieve a high butanol production by regulating the metabolism of carbon, redox or energy, (2) the challenges in pathway manipulation, and (3) the application of proteomics technology to understand the intracellular metabolism. In addition, the process engineering is also briefly described. The objective of this review is to summarize the previous research achievements in the metabolic engineering of and provide guidance for future novel strain construction to effectively produce butanol.

关键词： Clostridia     butanol     biofuel     metabolism     carbon     redox     energy    

HTML PDF 收藏

Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium redox

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1221-1230 doi: 10.1007/s11705-023-2298-8

摘要： The vanadium redox flow battery with a safe and capacity-controllable large-scale energy storage system offers a new method for the sustainability. In this case, acetic acid, methane sulfonic acid, sulfonic acid, amino methane sulfonic acid, and taurine are used to overcome the low electrolyte energy density and stability limitations, as well as to investigate the effects of various organic functional groups on the vanadium redox flow battery. When compared to the pristine electrolyte (0.22 Ah, 5.0 Wh·L–1, 85.0%), the results show that taurine has the advantage of maintaining vanadium ion concentrations, discharge capacity (1.43 Ah), energy density (33.9 Wh·L–1), and energy efficiency (90.5%) even after several cycles. The acetic acid electrolyte is more conducive to the low-temperature stability of the V(II) electrolyte (177 h at −25 °C) than pristine (82 h at −2 °C). The –SO3H group, specifically the coaction of the –NH2 and –SO3H groups, improves electrolyte stability. The –NH2 and –COOH additive groups improved conductivity and electrochemical activity.

关键词： vanadium redox flow battery     functional groups     organic additives     energy density     stability    

HTML PDF 收藏

Probing the redox process of

Rui Lu, Wei Chen, Wen-Wei Li, Guo-Ping Sheng, Lian-Jun Wang, Han-Qing Yu

《环境科学与工程前沿（英文）》 2017年 第11卷 第1期 doi: 10.1007/s11783-017-0905-y

摘要： Fluorescece spectroelectrochemistry is used to probe redox process of benzoquinone. The benzoquinone reduction state has a lower fluorescence quantum efficiency. CVF and DCVF can reveal more information about benzoquinone redox reactions. This method can analyze compounds with fluorescence and electrochemical activities. Quinones are common organic compounds frequently used as model dissolved organic matters in water, and their redox properties are usually characterized by either electrochemical or spectroscopic methods separately. In this work, electrochemical methodology was combined with two fluorescence spectroelectrochemical techniques, cyclic volta- fluorescence spectrometry (CVF) and derivative cyclic volta- fluorescence spectrometry (DCVF), to determine the electrochemical properties of -benzoquinone in dimethyl sulfoxide, an aprotic solution. The CVF results show that the electrochemical reduction of -benzoquinone resulted in the formation of radical anion and dianion, which exhibited a lower fluorescence intensity and red-shift of the emission spectra compared to that of -benzoquinone. The fluorescence intensity was found to vary along with the electrochemical oxidation and reduction of -benzoquinone. The CVF and DCVF results were in good consistence. Thus, the combined method offers a powerful tool to investigate the electrochemical process of -benzoquinone and other natural organic compounds.

关键词： p-Benzoquinone     Electrochemistry     Fluorescence     Spectroelectrochemistry     Derivative cyclic volta fluorescence    

HTML PDF 收藏

Nitrifying population dynamics in a redox stratified membrane biofilm reactor (RSMBR) for treating ammonium-rich

Rongchang WANG, Xinmin ZHAN, Yalei ZHANG, Jianfu ZHAO

《环境科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 48-56 doi: 10.1007/s11783-011-0305-7

摘要： Nitrogen removal performance and nitrifying population dynamics were investigated in a redox stratified membrane biofilm reactor (RSMBR) under oxygen limited condition to treat ammonium-rich wastewater. When the loading rate increased from 11.1±1.0 to , the nitrogen removal in the RSMBR system increased from 18.0±9.6 mgN·d to 128.9±61.7 mgN·d . Shortcut nitrogen removal was achieved with nitrite accumulation of about . Confocal micrographs showed the stratified distributions of nitrifiers and denitrifiers in the membrane aerated biofilms (MABs) at day 120, i.e., ammonia and nitrite oxidizing bacteria (AOB and NOB) were dominant in the region adjacent to the membrane, while heterotrophic bacteria propagated at the top of the biofilm. Real-time qPCR results showed that the abundance of gene was two orders of magnitude higher than the abundance of gene in the MABs. However, the gene was always detected during the operation time, which indicates the difficulty of complete washout of NOB in MABs. The growth of heterotrophic bacteria compromised the dominance of nitrifiers in biofilm communities, but it enhanced the denitrification performance of the RSMBR system. Applying a high ammonia loading together with oxygen limitation was found to be an effective way to start nitrite accumulation in MABs, but other approaches were needed to sustain or improve the extent of nitritation in nitrogen conversion in MABs.

关键词： ammonium-rich wastewater     membrane biofilm reactor     nitrification     redox stratification     shortcut nitrogen removal    

HTML PDF 收藏

Persistent free radicals in humin under redox conditions and their impact in transforming polycyclic

Hanzhong Jia, Yafang Shi, Xiaofeng Nie, Song Zhao, Tiecheng Wang, Virender K. Sharma

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1252-y

摘要： Abstract • Regulation of redox conditions promotes the generation of free radicals on HM. • HM-PFRs can be fractionated into active and inactive types depending on stability. • The newly produced PFRs readily release electrons to oxygen and generate ROS. • PFR-induced ROS mediate the transformation of organic contaminants adsorbed on HM. The role of humic substance-associated persistent free radicals (PFRs) in the fate of organic contaminants under various redox conditions remains unknown. This study examined the characterization of original metal-free peat humin (HM), and HM treated with varying concentrations of H2O2 and L-ascorbic acid (VC) (assigned as H2O2-HM and VC-HM). The concentration of PFRs in HM increased with the addition of VC/H2O2 at concentrations less than 0.08 M. The evolution of PFRs in HM under different environmental conditions (e.g., oxic/anoxic and humidity) was investigated. Two types of PFRs were detected in HM: a relatively stable radical existed in the original sample, and the other type, which was generated by redox treatments, was relatively unstable. The spin densities of VC/H2O2-HM readily returned to the original value under relatively high humidity and oxic conditions. During this process, the HM-associated “unstable” free radicals released an electron to O2, inducing the formation of reactive oxygen species (ROS, i.e., •OH and •O2−). The generated ROS promoted the degradation of polycyclic aromatic hydrocarbons based on the radical quenching measurements. The transformation rates followed the order naphthalene>phenanthrene>anthracene>benzo[a]pyrene. Our results provide valuable insight into the HM-induced transformation of organic contaminants under natural conditions.

关键词： Humic substance     Polycyclic aromatic hydrocarbons (PAHs)     Persistent free radicals (PFRs)     Redox     Reactive oxygen species (ROS)    

HTML PDF 收藏

Pressure drop analysis on the positive half-cell of a cerium redox flow battery using computational fluid

Fernando F. Rivera, Berenice Miranda-Alcántara, Germán Orozco, Carlos Ponce de León, Luis F. Arenas

《化学科学与工程前沿（英文）》 2021年 第15卷 第2期   页码 399-409 doi: 10.1007/s11705-020-1934-9

摘要： Description of electrolyte fluid dynamics in the electrode compartments by mathematical models can be a powerful tool in the development of redox flow batteries (RFBs) and other electrochemical reactors. In order to determine their predictive capability, turbulent Reynolds-averaged Navier-Stokes (RANS) and free flow plus porous media (Brinkman) models were applied to compute local fluid velocities taking place in a rectangular channel electrochemical flow cell used as the positive half-cell of a cerium-based RFB for laboratory studies. Two different platinized titanium electrodes were considered, a plate plus a turbulence promoter and an expanded metal mesh. Calculated pressure drop was validated against experimental data obtained with typical cerium electrolytes. It was found that the pressure drop values were better described by the RANS approach, whereas the validity of Brinkman equations was strongly dependent on porosity and permeability values of the porous media.

关键词： CFD simulation     porous media     porous electrode     pressure drop     redox flow battery    

HTML PDF 收藏

Redox flow batteries—Concepts and chemistries for cost-effective energy storage

Matthäa Verena HOLLAND-CUNZ, Faye CORDING, Jochen FRIEDL, Ulrich STIMMING

《能源前沿（英文）》 2018年 第12卷 第2期   页码 198-224 doi: 10.1007/s11708-018-0552-4

摘要： Electrochemical energy storage is one of the few options to store the energy from intermittent renewable energy sources like wind and solar. Redox flow batteries (RFBs) are such an energy storage system, which has favorable features over other battery technologies, e.g. solid state batteries, due to their inherent safety and the independent scaling of energy and power content. However, because of their low energy-density, low power-density, and the cost of components such as redox species and membranes, commercialised RFB systems like the all-vanadium chemistry cannot make full use of the inherent advantages over other systems. In principle, there are three pathways to improve RFBs and to make them viable for large scale application: First, to employ electrolytes with higher energy density. This goal can be achieved by increasing the concentration of redox species, employing redox species that store more than one electron or by increasing the cell voltage. Second, to enhance the power output of the battery cells by using high kinetic redox species, increasing the cell voltage, implementing novel cell designs or membranes with lower resistance. The first two means reduce the electrode surface area needed to supply a certain power output, thereby bringing down costs for expensive components such as membranes. Third, to reduce the costs of single or multiple components such as redox species or membranes. To achieve these objectives it is necessary to develop new battery chemistries and cell configurations. In this review, a comparison of promising cell chemistries is focused on, be they all-liquid, slurries or hybrids combining liquid, gas and solid phases. The aim is to elucidate which redox-system is most favorable in terms of energy-density, power-density and capital cost. Besides, the choice of solvent and the selection of an inorganic or organic redox couples with the entailing consequences are discussed.

关键词： electrochemical energy storage     redox flow battery     vanadium    

HTML PDF 收藏

Iron oxidation-reduction and its impacts on cadmium bioavailability in paddy soils: a review

Chunhua ZHANG, Ying GE, Huan YAO, Xiao CHEN, Minkun HU

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 509-517 doi: 10.1007/s11783-012-0394-y

摘要： Redox conditions in paddy soils may vary as they are submerged and drained during rice growth. This change may bring about reductive dissolution of iron (Fe) oxides and subsequent formation of secondary Fe-bearing minerals in rice paddies. The mobility and bioavailability of metal contaminants such as cadmium (Cd) in paddy soils are closely related to the chemical behaviors of Fe. Therefore, in this paper, advances in the study of paddy Fe redox transformations and their effects on Cd availability to rice are briefly reviewed. Current concepts presented in this review include the forms of Fe in paddy soils, the reactions involved in Fe oxidation-reduction, chemical factors affecting Fe redox processes, Cd availability to rice and the impacts of Fe transformation on Cd uptake and translocation in rice. Prospects for future research in this area are also discussed.

关键词： paddy soil     redox     iron     cadmium     bioavailability     rice    

HTML PDF 收藏

Redox reactions of iron and manganese oxides in complex systems

Jianzhi Huang, Huichun Zhang

《环境科学与工程前沿（英文）》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1255-8

摘要： • Mechanisms of redox reactions of Fe- and Mn-oxides were discussed. • Oxidative reactions of Mn- and Fe-oxides in complex systems were reviewed. • Reductive reaction of Fe(II)/iron oxides in complex systems was examined. • Future research on examining the redox reactivity in complex systems was suggested. Conspectus Redox reactions of Fe- and Mn-oxides play important roles in the fate and transformation of many contaminants in natural environments. Due to experimental and analytical challenges associated with complex environments, there has been a limited understanding of the reaction kinetics and mechanisms in actual environmental systems, and most of the studies so far have only focused on simple model systems. To bridge the gap between simple model systems and complex environmental systems, it is necessary to increase the complexity of model systems and examine both the involved interaction mechanisms and how the interactions affected contaminant transformation. In this Account, we primarily focused on (1) the oxidative reactivity of Mn- and Fe-oxides and (2) the reductive reactivity of Fe(II)/iron oxides in complex model systems toward contaminant degradation. The effects of common metal ions such as Mn2+ , Ca2+, Ni2+, Cr3+ and Cu2+, ligands such as small anionic ligands and natural organic matter (NOM), and second metal oxides such as Al, Si and Ti oxides on the redox reactivity of the systems are briefly summarized.

关键词： Iron oxides     manganese oxides     reduction     oxidation     complex systems     reaction kinetics and mechanisms    

HTML PDF 收藏

β-Nickel hydroxide cathode material for nano-suspension redox flow batteries

Yue LI, Cheng HE, Elena V. TIMOFEEVA, Yujia DING, Javier PARRONDO, Carlo SEGRE, Vijay RAMANI

《能源前沿（英文）》 2017年 第11卷 第3期   页码 401-409 doi: 10.1007/s11708-017-0496-0

摘要： As part of an effort to build a prototype flow battery system using a nano-suspension containing β-Ni(OH) nanoparticles as the cathode material, nano-sized β-Ni(OH) particles with well-controlled particle size and morphology were synthesized via the one-step precipitation of a NiCl precursor. The composition and morphology of the nanoparticles were characterized by scanning electronic microscopy (SEM) and X-ray diffraction (XRD). The XRD patterns confirmed that β-Ni(OH) was successfully synthesized, while SEM results showed that the particle sizes range from 70 to 150 nm. To ensure that Ni(OH) could be employed in the nano-suspension flow battery, the electrochemical performance of the synthesized β-Ni(OH) was initially tested in pouch cells through charge/discharge cycling. The phase transformations occurring during charge/discharge were investigated using X-ray absorption spectroscopy to obtain the shift in the oxidation state of Ni (X-ray adsorption near edge structure, XANES) and the distances between Ni and surrounding atoms in charged and discharged states (extended X-ray absorption fine structure, EXAFS). XANES results indicated that the electrode in the discharged state was a mixture of phases because the edge position did not shift back completely. XAFS results further proved that the discharge capacity was provided by β-NiOOH and the ratio between β-Ni(OH) and g-NiOOH in the electrode in the discharged state was 71:29. Preliminary nano-suspension tests in a lab-scale cell were conducted to understand the behavior of the nano-suspension during charge/discharge cycling and to optimize the operating conditions.

关键词： nano-suspension flow battery     β-Ni(OH)2     scanning electronic microscopy (SEM)     X-ray diffraction (XRD)     X-ray adsorption near edge structure (XANES)     extended X-ray absorption fine structure (EXAFS)    

HTML PDF 收藏

Preparation of ceria-zirconia solid solution with enhanced oxygen storage capacity and redox performance

Lijing MENG, Licheng LIU, Xuehong ZI, Hongxing DAI, Hong HE, Zhen ZHAO, Xinping WANG,

《环境科学与工程前沿（英文）》 2010年 第4卷 第2期   页码 164-171 doi: 10.1007/s11783-010-0019-2

摘要： A new method called ultrasonic-assisted membrane reaction (UAMR) was reported for the fabrication of ceria-zirconia solid solution. A series of ceria-zirconia solid solutions with different Ce/Zr molar ratios were prepared by the UAMR method and characterized by X-ray diffraction (XRD), N adsorption, hydrogen temperature-programmed reduction (H-TPR), scanning electron microscope (SEM), and transmission electron microscopy (TEM) techniques. The UAMR method proved to be superior, especially when the Ce/Zr molar ratio was lower than 1, in fabricating ceria-zirconia solid solutions with large BET surface area, high oxygen storage capacity (OSC), and low reduction temperature.

关键词： membrane reaction     ceria-zirconia     Ce/Zr molar ratio     solid solution     hydrogen temperature-programmed reduction (H2-TPR)    

HTML PDF 收藏

Simultaneous enhanced ammonia and nitrate removal from secondary effluent in constructed wetlands using a new manganese-containing substrate

《环境科学与工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1807-4

摘要：

● MnO2/PCL composite material (MPCM) enhances ammonia and nitrate removal in CWs.

关键词： Constructed wetland     Nitrogen removal     Manganese redox     Polycaprolactone     Nitrous oxide    

HTML PDF 收藏

Emerging electrochemical processes for materials recovery from wastewater: Mechanisms and prospects

Lingchen Kong, Xitong Liu

《环境科学与工程前沿（英文）》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1269-2

摘要： Abstract • Mechanisms for selective recovery of materials in electrochemical processes are discussed. • Wastewaters that contain recoverable materials are reviewed. • Application prospects are discussed from both technical and non-technical aspects. Recovering valuable materials from waste streams is critical to the transition to a circular economy with reduced environmental damages caused by resource extraction activities. Municipal and industrial wastewaters contain a variety of materials, such as nutrients (nitrogen and phosphorus), lithium, and rare earth elements, which can be recovered as value-added products. Owing to their modularity, convenient operation and control, and the non-requirement of chemical dosage, electrochemical technologies offer a great promise for resource recovery in small-scale, decentralized systems. Here, we review three emerging electrochemical technologies for materials recovery applications: electrosorption based on carbonaceous and intercalation electrodes, electrochemical redox processes, and electrochemically induced precipitation. We highlight the mechanisms for achieving selective materials recovery in these processes. We also present an overview of the advantages and limitations of these technologies, as well as the key challenges that need to be overcome for their deployment in real-world systems to achieve cost-effective and sustainable materials recovery.

关键词： Materials recovery     Electrosorption     Capacitive deionization     Redox processes     Electrochemical precipitation    

HTML PDF 收藏

Oxidative stress and diabetes: antioxidative strategies

Pengju Zhang, Tao Li, Xingyun Wu, Edouard C. Nice, Canhua Huang, Yuanyuan Zhang

《医学前沿（英文）》 2020年 第14卷 第5期   页码 583-600 doi: 10.1007/s11684-019-0729-1

摘要： Diabetes mellitus is one of the major public health problems worldwide. Considerable recent evidence suggests that the cellular reduction–oxidation (redox) imbalance leads to oxidative stress and subsequent occurrence and development of diabetes and related complications by regulating certain signaling pathways involved in β-cell dysfunction and insulin resistance. Reactive oxide species (ROS) can also directly oxidize certain proteins (defined as redox modification) involved in the diabetes process. There are a number of potential problems in the clinical application of antioxidant therapies including poor solubility, storage instability and non-selectivity of antioxidants. Novel antioxidant delivery systems may overcome pharmacokinetic and stability problem and improve the selectivity of scavenging ROS. We have therefore focused on the role of oxidative stress and antioxidative therapies in the pathogenesis of diabetes mellitus. Precise therapeutic interventions against ROS and downstream targets are now possible and provide important new insights into the treatment of diabetes.

关键词： diabetes     oxidative stress     redox modification     antioxidative therapy     novel antioxidant delivery    

HTML PDF 收藏

标题 作者 时间 类型 操作

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

期刊论文

High butanol production by regulating carbon, redox and energy in Clostridia? ?

Jianfa Ou,Chao Ma,Ningning Xu,Yinming Du,Xiaoguang (Margaret) Liu

期刊论文

Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium redox

期刊论文

Probing the redox process of

Rui Lu, Wei Chen, Wen-Wei Li, Guo-Ping Sheng, Lian-Jun Wang, Han-Qing Yu

期刊论文

Nitrifying population dynamics in a redox stratified membrane biofilm reactor (RSMBR) for treating ammonium-rich

Rongchang WANG, Xinmin ZHAN, Yalei ZHANG, Jianfu ZHAO

期刊论文

Persistent free radicals in humin under redox conditions and their impact in transforming polycyclic

Hanzhong Jia, Yafang Shi, Xiaofeng Nie, Song Zhao, Tiecheng Wang, Virender K. Sharma

期刊论文

Pressure drop analysis on the positive half-cell of a cerium redox flow battery using computational fluid

Fernando F. Rivera, Berenice Miranda-Alcántara, Germán Orozco, Carlos Ponce de León, Luis F. Arenas

期刊论文

Redox flow batteries—Concepts and chemistries for cost-effective energy storage

Matthäa Verena HOLLAND-CUNZ, Faye CORDING, Jochen FRIEDL, Ulrich STIMMING

期刊论文

Iron oxidation-reduction and its impacts on cadmium bioavailability in paddy soils: a review

Chunhua ZHANG, Ying GE, Huan YAO, Xiao CHEN, Minkun HU

期刊论文

Redox reactions of iron and manganese oxides in complex systems

Jianzhi Huang, Huichun Zhang

期刊论文

β-Nickel hydroxide cathode material for nano-suspension redox flow batteries

Yue LI, Cheng HE, Elena V. TIMOFEEVA, Yujia DING, Javier PARRONDO, Carlo SEGRE, Vijay RAMANI

期刊论文

Preparation of ceria-zirconia solid solution with enhanced oxygen storage capacity and redox performance

Lijing MENG, Licheng LIU, Xuehong ZI, Hongxing DAI, Hong HE, Zhen ZHAO, Xinping WANG,

期刊论文

Simultaneous enhanced ammonia and nitrate removal from secondary effluent in constructed wetlands using a new manganese-containing substrate

期刊论文

Emerging electrochemical processes for materials recovery from wastewater: Mechanisms and prospects

Lingchen Kong, Xitong Liu

期刊论文

Oxidative stress and diabetes: antioxidative strategies

Pengju Zhang, Tao Li, Xingyun Wu, Edouard C. Nice, Canhua Huang, Yuanyuan Zhang

期刊论文