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期刊论文 13

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上游操作 1

严格建模 1

作用机理 1

力矩反馈器 1

化学机械抛光 1

压阻器件 1

叔胺 1

复合磨粒 1

微加工工艺 1

微型传感器 1

微机电系统 1

成果与进展 1

抛光液 1

油包水乳剂 1

浮选 1

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The electrostatic-alloy bonding technique used in MEMS

WANG Wei, CHEN Wei-ping

《机械工程前沿（英文）》 2006年 第1卷 第2期   页码 238-241 doi: 10.1007/s11465-006-0011-5

摘要： Electrostatic-alloy bonding of silicon wafer with glass deposited by Au to form Si/Au-glass water, and bonding of Si/Au-glass with silicon wafer were researched during fabrication of pressure sensors. The silicon wafer and glass wafer with an Au film resistor were bonded by electrostatic bonding, and then Si-Au alloy bonding was formed by annealing at 400vH for 2 h. The air sealability of the cavity after bonding was finally tested using the N filling method. The results indicate that large bond strength was obtained at the bonding interface. This process was used in fabricating a pressure sensor with a sandwich structure. The results indicate that the sensor presented better performances and that the bonding techniques can be used in MEMS packaging.

关键词： Si/Au-glass     strength     MEMS packaging     process     sandwich structure    

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静电防护工程的研究与进展

刘尚合,谭志良,武占成

《中国工程科学》 2000年 第2卷 第11期   页码 17-24

摘要：

静电放电已成为信息化时代的公害之一，它不仅是危险场所的点火源、引爆源，而且是信息化设备的电磁干扰源。文章在论述静电放电危害、静电放电的特点、作用机理和形成静电危害基本条件的同时，报道了我国在静电检测与静电防护工程研究方面的成果与进展，提出了“信号自屏蔽-电荷耦合”测试原理、真实静电感度测试方法、织物电位测试方法和人体静电动态电位测试技术，建立了电火工品静电发火数理模型、“静电危险场所”等级划分标准和分类防护措施、预测静电危害的逻辑关系图和静电防护的一般原则与对策。文章介绍了部分实验数据和该领域当前研究的热点问题及发展趋势。

关键词： 静电危害     作用机理     防护工程     成果与进展    

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硅微z轴谐振陀螺仪负电刚度效应分析及实验验证

夏敦柱,周百令,王寿荣

《中国工程科学》 2007年 第9卷 第8期   页码 66-68

摘要：

介绍了在开环工作状态下硅微z轴谐振陀螺仪由于加工工艺缺陷所导致的误差机理。为减小陀螺仪初始电容差和抑制正交耦合误差，提出了一种闭环控制检测策略。重点分析了其力矩反馈器的电刚度效应并给出其线性数学模型表示式。通过对硅微z轴陀螺仪敏感模态的反馈力与谐振频率的关系分析，间接得出了在敏感方向上电负刚度与力矩器所施电压的内在联系，并在实验上进一步验证电刚度效应。这将为下一步闭环控制方案的设计奠定重要基础。

关键词： 硅微z轴陀螺仪     负电刚度     力矩反馈器     微机电系统    

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炼油工业中的上游操作：静电聚结器的严格建模

Rossi Francesco, Colombo Simone, Pierucci Sauro, Ranzi Eliseo, Manenti Flavio

《工程（英文）》 2017年 第3卷 第2期   页码 220-231 doi: 10.1016/J.ENG.2017.02.013

摘要：

在炼油工业的上游操作中，静电聚结器装置被用来将油包水乳剂中的水从油中分离出来。本文从基本原理出发对影响静电聚结器性能的主要现象进行了描述，并主要针对静电聚结器装置建立了数学机理模型。另外，乳剂液滴的逐步凝结也以动态的形式在建模中被考虑进来，因为这一现象是影响装置操作整体收率的关键步骤。所建的差分系统及其边界条件被用来产生数值解，仿真结果证实了现有文献和工业数据，并针对主要参数进行了灵敏度分析。该数学模型在装置的设计、反应预测、性能监控以及优化中都能起到良好的作用。

关键词： 上游操作     静电聚结器     脱盐     严格建模     油包水乳剂    

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Kinetics of enhanced adsorption by polarization for organic pollutants on activated carbon fiber

HAN Yanhe, QUAN Xie, ZHAO Huimin, CHEN Shuo, ZHAO Yazhi

《环境科学与工程前沿（英文）》 2007年 第1卷 第1期   页码 83-88 doi: 10.1007/s11783-007-0016-2

摘要： The adsorption kinetics for model pollutants on activated carbon fiber (ACF) by polarization was investigated in this work. Kinetics data obtained for the adsorption of these model pollutants at open-circuit, 400 mV, and -400 mV polarization were applied to the Lagergren equation, and adsorption rate constants () were determined. With the anodic polarization of 400 mV, the capacity of sodium phenoxide was increased from 0.0083 mmol/g at open-circuit to 0.18 mmol/g, and a 17-fold enhancement was achieved; however, the capacity of -nitrophenol was decreased from 2.93 mmol/g at open-circuit to 2.65 mmol/g. With the cathodal polarization of -400 mV, the capacity of aniline was improved from 3.60 mmol/g at open-circuit to 3.88 mmol/g; however, the capacity of sodium dodecylbenzene sulfonate was reduced from 2.20 mmol/g at open-circuit to 1.59 mmol/g. The enhancement for electrosorption changed with dif ferent groups substituting. Anodic polarization enhances the adsorption of benzene with the electron-donating group. But whether anodic or not, cathodal polarization had less effect on the adsorption of electron-accepting aromatic compounds, and decreased the adsorption capacity of benzene-bearing donor-conjugate bridge-acceptor, while increasing its adsorption rate. Electrostatic interaction played a very important role in the electrosorption of ion-pollutants.

关键词： ACF     activated     17-fold enhancement     donor-conjugate bridge-acceptor     Electrostatic interaction    

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A density functional theory study of the adsorption of Hg and HgCl2 on a CaO(001) surface

GUO Xin, ZHENG Chuguang, LU Nanxia

《能源前沿（英文）》 2007年 第1卷 第1期   页码 101-104 doi: 10.1007/s11708-007-0011-0

摘要： The adsorption of mercury and mercury chloride on a CaO(001) surface was investigated by the density functional theory (DFT) by using CaO cluster embedded in an electrostatic field represented by 178 point charges at the crystal CaO lattice positions. For the mercury molecular axis normal to the surface, the mercury can only coordinate to the O anion and has a very weak binding energy of 19.649 kJ/mol. When the mercury chloride molecular axis is vertical to the surface, the Cl atom coordinates to the Ca cation and has a binding energy of 23.699 kJ/mol. When the mercury chloride molecular axis is parallel to the surface, the Hg atom coordinates to the O anion and has a binding energy of 87.829 kJ/mol, which means that the parallel geometry is more stable than the vertical one. The present calculations show that CaO injection could substantially reduce gaseous mercury chloride, but have no apparent effect on the mercury, which is compatible with the available experimental results. This research will provide valuable information for optimizing and selecting a sorbent for the trace element in flue gas.

关键词： mercury chloride     mercury molecular     surface     cluster     electrostatic    

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静电力驱动的悬臂梁微型电场传感器件 Article

韩志飞, 胡军, 李立浧, 何金良

《工程（英文）》 2023年 第24卷 第5期   页码 184-191 doi: 10.1016/j.eng.2022.06.017

摘要：

随着智能电网和能源互联网的发展，大规模实时电压/电场监测成为电力系统的迫切需求，这依赖于先进传感器件的大规模布置。电场测量在电力系统中具有重要意义。一方面，基于电场测量的电压反演可以实现高电压的非接触式测量，替代传统高压互感器，从而减少测量设备绝缘成本和安装难度；另一方面，电场测量还可以被应用于设备故障诊断、雷电预警、电磁环境测量等应用场景。传统的电场测量设备，如场磨等，往往体积大、成本高，无法大规模灵活布置。本文提出了一种静电力驱动的压阻式微型电场传感器。传感器被设计为四悬臂结构，悬臂在静电力的驱动下产生位移和应变，通过压阻材料转化为可测信
号。所提出的传感器具有尺寸小、成本低、功耗低、易于批量生产的优点。同时，该传感器还具有高信噪比、高分辨率及宽电场测量范围的特点。实验结果表明，所提出的传感器具有1.1~1100.0 kV·m−1的线性测量范围、112 V·m−1·Hz−1/2的交流电场分辨率以及496 Hz的截止频率。这一微型电场传感器将在智能电网及能源互联网中具有广泛的应用价值。

关键词： 微型传感器     电气传感器件     微加工工艺     压阻器件    

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Review of characterization and modeling of polymer electrolyte fuel cell catalyst layer: The blessing and curse of ionomer

Jun HUANG, Zhe LI, Jianbo ZHANG

《能源前沿（英文）》 2017年 第11卷 第3期   页码 334-364 doi: 10.1007/s11708-017-0490-6

摘要： Ionomer impregnation represents a milestone in the evolution of polymer electrolyte fuel cell (PEFC) catalyst layers. Ionomer acts as the binder, facilitates proton transport, and thereby drastically improves catalyst utilization and effectiveness. However, advanced morphological and functional characterizations have revealed that up to 60% of Pt nanoparticles can be trapped in the micropores of carbon support particles. Ionomer clusters and oxygen molecules can hardly enter into micropores, leading to low Pt utilization and effectiveness. Moreover, the ionomer thin-films covering Pt nanoparticles can cause significant mass transport loss especially at high current densities. Ionomer-free ultra-thin catalyst layers (UTCLs) emerge as a promising alternative to reduce Pt loading by improving catalyst utilization and effectiveness, while theoretical issues such as the proton conduction mechanism remain puzzling and practical issues such as the rather narrow operation window remain unsettled. At present, the development of PEFC catalyst layer has come to a crossroads: staying ionomer-impregnated or going ionomer-free. It is always beneficial to look back into the past when coming to a crossroads. This paper addresses the characterization and modeling of both the conventional ionomer-impregnated catalyst layer and the emerging ionomer-free UTCLs, featuring advances in characterizing microscale distributions of Pt particles, ionomer, support particles and unraveling their interactions; advances in fundamental understandings of proton conduction and flooding behaviors in ionomer-free UTCLs; advances in modeling of conventional catalyst layers and especially UTCLs; and discussions on high-impact research topics in characterizing and modeling of catalyst layers.

关键词： polymer electrolyte fuel cell     ultra-thin catalyst layer     electrostatic interactions     characterization and modeling     structure-property-performance relation     water management    

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Modeling of the separation performance of nanofiltration membranes and its role in the applications of nanofiltration technology in product separation processes

SHANG Weijuan, WANG Daxin, WANG Xiaolin

《化学科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 208-215 doi: 10.1007/s11705-007-0038-0

摘要： Although there is a voluminous literature on the determination of structural parameters (the pore radius, the ratio of membrane porosity to membrane thickness) of a nanofiltration (NF) membrane and its separation performance (such as the rejection and the permeation flux) by the simplified Teorell-Meyer-Sievers (TMS) model, little of this research comments on other theories and the consequences of linking modeling evaluation to technological application. Theories used to predict the separation performance of an NF membrane usually include: the non-equilibrium thermodynamic model, the pore model, the space charge model, the TMS model, the electrostatic and steric-hindrance model, and the semiempirical model. In the article, we briefly trace the origins or the general ideas of the above-mentioned theories. From there, recent researches on the characterization of membrane structural parameters and electrical properties (such as the surface charge density ) are reviewed. We then turn to research on the separation performance of an NF membrane for single-component solutions of inorganic electrolytes, neutral organic solutions, and a mixture solution of electrolytes or that of an electrolyte and neutral organic solute. Afterwards, we outline the applications of NF technology in the processes of product separation and conclude with a discussion on the role of models in such applications.

关键词： above-mentioned     TMS     characterization     electrostatic     semiempirical    

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Selective sorption of perfluorooctane sulfonate on molecularly imprinted polymer adsorbents

Shubo DENG, Danmeng SHUAI, Qiang YU, Jun HUANG, Gang YU

《环境科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 171-177 doi: 10.1007/s11783-009-0017-4

摘要： Perfluorooctane sulfonate (PFOS), as a potential persistent organic pollutant, has been widely detected in water environments, and has become a great concern in recent years. PFOS is very stable and difficult to decompose using conventional techniques. Sorption may be an attractive method to remove it from water. In this study, the molecularly imprinted polymer (MIP) adsorbents were prepared through the polymerization of 4-vinylpyridine under different preparation conditions in order to remove perfluorooctane sulfonate (PFOS) from water. The MIP adsorbents using perfluorooctanoic acid (PFOA) as the template had good imprinting effects and could selectively remove PFOS from aqueous solution. The sorption behaviors including sorption kinetics, isotherms, and effect of pH, salt, and competitive anions were investigated. Experimental results showed that the sorption of PFOS on the MIP adsorbents was very fast, pH-dependent, and highly selective. The achieved fast sorption equilibrium within 1 h was attributed to the surface sorption on the fine adsorbents. The sorption isotherms showed that the sorption selectivity of PFOS on the MIP adsorbents decreased at high PFOS concentrations, which may be due to the double-layer sorption and the formation of PFOS micelles on the sorbent surface. The sorption of PFOS on the MIP adsorbents was mainly dominated by the electrostatic interaction between the protonated vinylpyridine on the adsorbent surface and the anionic PFOS. The prepared MIP adsorbents can potentially be applied in water and wastewater treatment for selective removal of PFOS.

关键词： perfluorooctane sulfonate (PFOS)     molecularly imprinted polymer (MIP) adsorbents     selective sorption     electrostatic interaction    

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Removal of clofibric acid from aqueous solution by polyethylenimine-modified chitosan beads

Yao NIE,Shubo DENG,Bin WANG,Jun HUANG,Gang YU

《环境科学与工程前沿（英文）》 2014年 第8卷 第5期   页码 675-682 doi: 10.1007/s11783-013-0622-0

摘要： Polyethylenimine (PEI)-modified chitosan was prepared and used to remove clofibric acid (CA) from aqueous solution. PEI was chemically grafted on the porous chitosan through a crosslinking reaction, and the effects of PEI concentration and reaction time in the preparation on the adsorption of clofibric acid were optimized. Scanning electron microscopy (SEM) showed that PEI macromolecules were uniformly grafted on the porous chitosan, and the analysis of pore size distribution indicated that more mesopores were formed due to the crosslinking of PEI molecules in the macropores of chitosan. The PEI-modified chitosan had fast adsorption for CA within the initial 5 h, while this adsorbent exhibited an adsorption capacity of 349 mg·g for CA at pH 5.0 according to the Langmuir fitting, higher than 213 mg·g on the porous chitosan. The CA adsorption on the PEI-modified chitosan was pH-dependent, and the maximum adsorption was achieved at pH 4.0. Based on the surface charge analysis and comparison of different pharmaceuticals adsorption, electrostatic interaction dominated the sorption of CA on the PEI-modified chitosan. The PEI-modified chitosan has a potential application for the removal of some anionic micropollutants from water or wastewater.

关键词： clofibric acid     PEI-modified chitosan     adsorption capacity     adsorption mechanism     electrostatic interaction    

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静电自组装制备复合磨粒及其对铜的抛光特性研究

黄亦申,许雪峰,姚春燕,胡建德,彭伟

《中国工程科学》 2012年 第14卷 第10期   页码 82-89

摘要：

研究苯代三聚氰胺甲醛（BGF）微球与阳离子型聚电解质聚二烯丙基二甲基氯化铵（PDADMAC）、阴离子型聚电解质聚4－苯乙烯璜酸钠（PSS）之间的吸附特性，利用静电自组装技术改变和控制BGF微球的荷电特性，制备出不同形式的PEi BGF/SiO2复合磨粒，以Zeta电位、透射电子显微镜（TEM）和热重分析（TG）等手段对复合磨粒进行了表征，并利用这些复合磨粒制备了铜片抛光用的复合磨粒抛光液。抛光试验表明，吸附在聚合物微球表面和游离于抛光液中的SiO2磨粒在抛光中均起到材料去除作用。传统单一SiO2磨粒抛光液的铜材料去除率为264 nm/min，PE0 BGF/SiO2混合磨粒抛光液的铜材料去除率为348 nm/min，PE3 BGF/SiO2复合磨粒抛光液的铜材料去除率为476 nm/min。经上述3种抛光液抛光后的铜表面，在5 μm×5 μm范围内，表面粗糙度Ra从0.166 μm分别降至3.7 nm、2.6 nm和1.5 nm，峰谷值Rpv分别小于20 nm、14 nm和10 nm，复合磨粒抛光液对铜片有良好的抛光性能。

关键词： 化学机械抛光     抛光液     复合磨粒     聚电解质     铜片    

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十二系列叔胺捕收剂对高岭石的浮选研究

曹学锋,刘长淼,胡岳华

《中国工程科学》 2011年 第13卷 第1期   页码 93-97

摘要：

研究4种十二取代叔胺（DRN，DEN，DPN和DBN）对高岭石的浮选行为。发现4种叔胺对高岭石的浮选捕收能力都较好，其中DEN最好，浮选回收率最高可达92 %以上。4种叔胺主要依靠静电引力吸附在高岭石表面，在酸性pH范围内，浮选高岭石的回收率较高，随着pH的增大，叔胺的阳离子组分减少，使得浮选回收率下降。Zeta电位研究表明，高岭石在整个pH范围内，表面主要带负电，4种叔胺与高岭石作用后，能显著增加高岭石的Zeta电位。红外光谱研究表面，4种叔胺主要与高岭石表面发生了电性作用的物理吸附。叔胺中N原子上的取代基的给电子效应和空间位阻效应是造成 4 种叔胺浮选能力差异的主要原因。

关键词： 叔胺     高岭石     浮选     静电作用     电子效应     空间效应    

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标题 作者 时间 类型 操作

The electrostatic-alloy bonding technique used in MEMS

WANG Wei, CHEN Wei-ping

期刊论文

静电防护工程的研究与进展

刘尚合,谭志良,武占成

期刊论文

硅微z轴谐振陀螺仪负电刚度效应分析及实验验证

夏敦柱,周百令,王寿荣

期刊论文

炼油工业中的上游操作：静电聚结器的严格建模

Rossi Francesco, Colombo Simone, Pierucci Sauro, Ranzi Eliseo, Manenti Flavio

期刊论文

Kinetics of enhanced adsorption by polarization for organic pollutants on activated carbon fiber

HAN Yanhe, QUAN Xie, ZHAO Huimin, CHEN Shuo, ZHAO Yazhi

期刊论文

A density functional theory study of the adsorption of Hg and HgCl2 on a CaO(001) surface

GUO Xin, ZHENG Chuguang, LU Nanxia

期刊论文

静电力驱动的悬臂梁微型电场传感器件

韩志飞, 胡军, 李立浧, 何金良

期刊论文

Review of characterization and modeling of polymer electrolyte fuel cell catalyst layer: The blessing and curse of ionomer

Jun HUANG, Zhe LI, Jianbo ZHANG

期刊论文

Modeling of the separation performance of nanofiltration membranes and its role in the applications of nanofiltration technology in product separation processes

SHANG Weijuan, WANG Daxin, WANG Xiaolin

期刊论文

Selective sorption of perfluorooctane sulfonate on molecularly imprinted polymer adsorbents

Shubo DENG, Danmeng SHUAI, Qiang YU, Jun HUANG, Gang YU

期刊论文

Removal of clofibric acid from aqueous solution by polyethylenimine-modified chitosan beads

Yao NIE,Shubo DENG,Bin WANG,Jun HUANG,Gang YU

期刊论文

静电自组装制备复合磨粒及其对铜的抛光特性研究

黄亦申,许雪峰,姚春燕,胡建德,彭伟

期刊论文

十二系列叔胺捕收剂对高岭石的浮选研究

曹学锋,刘长淼,胡岳华

期刊论文